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Maier U.,University of Tubingen | Maier U.,Helmholtz Center for Environmental Research | Flegr M.,University of Tubingen | Rugner H.,Water and Earth System Science Competence Cluster WESS | Grathwohl P.,University of Tubingen
Environmental Earth Sciences | Year: 2013

The impact of diffuse pollution, agricultural land use and climate change on the long-term response of subsurface-surface water quality is not well understood, but is a prerequisite for evaluation of water management options. The goal of this study is to model geochemical evolution of water chemistry from the infiltration through soil into the unsaturated zone, transport through bedrocks and granular aquifers to a river in order to identify zones of steep concentration gradients and high dynamics under transient flow conditions. A numerical model was constructed comprising a 2-D 1,500 m × 150 m vertical cross-section of typical sedimentary rock formations, a glacio-fluvial quaternary gravel aquifer in the valley and soil layers. The model coupled saturated/un-saturated flow and reactive transport under steady state and transient conditions. Geochemical interactions, include intra-aqueous kinetic reactions of oxygen with dissolved organic matter, as well as kinetics of carbonate dissolution/precipitation. This model section was chosen to provide insight in to the principal processes and time scales affecting water chemistry along different flow paths. The numerical simulator MIN3P was used, a finite volume program for variably saturated subsurface flow and multi-component reactive transport. The results show that subsurface water residence times range from approximately 2 to 2,000 years. Different zones are to be expected with respect to the development of mineral equilibria; namely, purely atmospherically influenced, as well as open and closed system carbonate dissolution. Short-term responses to daily averaged changes in precipitation, however, are only visible to some extent in the shallower and near-river parts of flow system and solute loads. This can most likely be explained by directional changes in flow paths, indicating that equilibrium geochemical condition predominate at the hillslope scale, i. e. water quality depends on transport pathways rather than on kinetic effects. The extent of reducing conditions is controlled by the presence of organic-rich layers (i. e. peat deposits), the dissolution kinetics of aquifer organic matter and the subsequent mixing with oxygenated water by hydrodynamic dispersion. © 2013 Springer-Verlag Berlin Heidelberg. Source


Liu Y.,Tongji University | Beckingham B.,University of Tubingen | Ruegner H.,Water and Earth System Science Competence Cluster WESS | Li Z.,Tongji University | And 5 more authors.
Environmental Science and Technology | Year: 2013

As a proxy to trace the impact of anthropogenic activity, sedimentary polycyclic aromatic hydrocarbons (PAHs) are compared between the early industrialized and newly industrialized countries of Germany and China, respectively. Surface sediment samples in the Ammer River of Germany and the Liangtan River of China were collected to compare concentration levels, distribution patterns, and diagnostic plots of sedimentary PAHs. Total concentrations of 16 PAHs in Ammer sediments were significantly higher by a factor of ∼4.5 than those in Liangtan. This contrast agrees with an extensive literature survey of PAH levels found in Chinese versus European sediments. Distribution patterns of PAHs were similar across sites in the Ammer River, whereas they were highly varied in the Liangtan River. Pyrogenic sources dominated in both cases. Strong correlations of the sum of 16 PAHs and PAH groups with TOC contents in the Liangtan River may indicate coemission of PAHs and TOC. Poor correlations of PAHs with TOC in the Ammer River indicate that other factors exert stronger influences. Sedimentary PAHs in the Ammer River are primarily attributed to input of diffuse sources or legacy pollution, while sediments in the Liangtan River are probably affected by ongoing point source emissions. Providing further evidence of a more prolonged anthropogenic influence are the elevated black carbon fractions in sedimentary TOC in the Ammer compared to the Liangtan. This implies that the Liangtan River, like others in newly industrialized regions, still has a chance to avoid legacy pollution of sediment which is widespread in the Ammer River and other European waterways. © 2012 American Chemical Society. Source


Gayler S.,Water and Earth System Science Competence Cluster WESS | Gayler S.,Lincoln Agritech Ltdruakura Research Center | Wohling T.,Water and Earth System Science Competence Cluster WESS | Grzeschik M.,Water and Earth System Science Competence Cluster WESS | And 11 more authors.
Water Resources Research | Year: 2014

Interactions between the soil, the vegetation, and the atmospheric boundary layer require close attention when predicting water fluxes in the hydrogeosystem, agricultural systems, weather, and climate. However, land-surface schemes used in large-scale models continue to show deficiencies in consistently simulating fluxes of water and energy from the subsurface through vegetation layers to the atmosphere. In this study, the multiphysics version of the Noah land-surface model (Noah-MP) was used to identify the processes, which are most crucial for a simultaneous simulation of water and heat fluxes between land surface and the lower atmosphere. Comprehensive field data sets of latent and sensible heat fluxes, ground heat flux, soil moisture, and leaf area index from two contrasting field sites in South-West Germany are used to assess the accuracy of simulations. It is shown that an adequate representation of vegetation-related processes is the most important control for a consistent simulation of energy and water fluxes in the soil-plant-atmosphere system. In particular, using a newly implemented submodule to simulate root growth dynamics has enhanced the performance of Noah-MP. We conclude that further advances in the representation of leaf area dynamics and root/soil moisture interactions are the most promising starting points for improving the simulation of feedbacks between the subsoil, land surface and atmosphere in fully coupled hydrological and atmospheric models. Key Points Selecting different model options strongly influences accuracy of simulations The ensemble size can be reduced by constraining Noah-MP to different data types Considering dynamics of root growth results in more accurate simulations © 2014. American Geophysical Union. All Rights Reserved. Source


Grathwohl P.,Water and Earth System Science Competence Cluster WESS | Grathwohl P.,University of Tubingen | Rugner H.,Water and Earth System Science Competence Cluster WESS | Wohling T.,Water and Earth System Science Competence Cluster WESS | And 38 more authors.
Environmental Earth Sciences | Year: 2013

Sustainable water quality management requires a profound understanding of water fluxes (precipitation, run-off, recharge, etc.) and solute turnover such as retention, reaction, transformation, etc. at the catchment or landscape scale. The Water and Earth System Science competence cluster (WESS, http://www.wess.info/) aims at a holistic analysis of the water cycle coupled to reactive solute transport, including soil-plant-atmosphere and groundwater-surface water interactions. To facilitate exploring the impact of land-use and climate changes on water cycling and water quality, special emphasis is placed on feedbacks between the atmosphere, the land surface, and the subsurface. A major challenge lies in bridging the scales in monitoring and modeling of surface/subsurface versus atmospheric processes. The field work follows the approach of contrasting catchments, i. e. neighboring watersheds with different land use or similar watersheds with different climate. This paper introduces the featured catchments and explains methodologies of WESS by selected examples. © 2013 Springer-Verlag Berlin Heidelberg. Source

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