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Angel Cid J.,University Jan | Pouso O.L.,University of Santiago de Compostela | Pouso R.L.,University of Santiago de Compostela
Nonlinear Analysis: Real World Applications | Year: 2011

We prove the existence of infinitely many solutions for a second-order singular initial value problem between given lower and upper solutions. Our study is motivated by a singular problem which arises in the field of nonlinear massive gravity. Moreover, we also discuss the global behavior of solutions of the motivating problem. Our arguments lean at some steps on lower and upper solutions with corners in their graphs, thus showing the applicability of this more general definition of lower and upper solutions in the analysis of a concrete mathematical model. © 2011 Elsevier Ltd. All rights reserved. Source


Garzon A.,University Jan | Granadino-Roldan J.M.,University Jan | Moral M.,University Jan | Garcia G.,University Jan | And 4 more authors.
Journal of Chemical Physics | Year: 2010

In the present work, we have studied from a theoretical perspective the geometry and electronic properties of the series of related compounds 2,5-bis(phenylethynyl)-1,3,4-thiadiazole, 2,5-bis(phenylethynyl)-1,3,4- oxadiazole, and 2,5-bis(phenylethynyl)-1,2,4-triazole as candidates for electron-conducting polymers and compounds with desirable (opto)electronic properties. The effect of the ethynyl group (-C≡C-) on the structure and electronic properties was also studied. The influence of planarity on electrical conductivity has been studied by a natural-bond-orbital analysis. The (opto)electronic properties and conducting capability were investigated through the highest occupied molecular orbital (HOMO)-lowest unoccupied molecular orbital (LUMO) gap, excitation energy, bond length alternation, LUMO energy, electron affinities, and intramolecular reorganization energy. Finally, the evolution of some properties such as optical bandgap and electron affinity with the increase of the number of repeat units in the oligomer chain has been checked. © 2010 American Institute of Physics. Source

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