Toyo Kohan Co.

Kudamatsu, Japan

Toyo Kohan Co.

Kudamatsu, Japan

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Provided are a surface-treated metal sheet which includes a nickel layer having improved corrosion resistance and a method of manufacturing a formed article. In a surface-treated metal sheet where a nickel layer is formed on a substrate, the proportion of the (200) plane to a total of the (111) plane, (200) plane, (220) plane and (311) plane with respect to the crystal plane orientations of the nickel layer is set to 40% or less. In a method of manufacturing a formed article using a surface-treated metal sheet where a nickel layer is formed on a substrate, the surface-treated metal sheet having the nickel layer where the proportion of the (200) plane to a total of the (111) plane, (200) plane, (220) plane and (311) plane is set to 40% or less with respect to the crystal plane orientations of the nickel layer is worked using a mold.


Patent
Toyo Kohan Co. | Date: 2017-02-08

An object of the present invention is to provide a production method for efficiently producing a metal laminate having high bonding strength. A method for producing a metal laminate material comprising the steps of: sputter etching faces to be bonded of a stainless steel and an aluminum such that an oxide layer remains on each face; temporarily bonding the faces to be bonded of the stainless steel and the aluminum by roll pressure bonding; and thermally treating the temporarily bonded laminate material at a temperature lower than the recrystallization temperature of the stainless steel to thermally diffuse at least a metal element comprised in the stainless steel into the aluminum.


Patent
Toyo Kohan Co. | Date: 2017-02-08

An object of the present invention is to provide a method for producing a metal laminate material that maintains sufficient bonding strength and has superior production efficiency. A method for producing a metal laminate material by bonding two sheets, one sheet composed of a material M1 and the other sheet composed of a material M2, wherein each of M1 and M2 is a metal or alloy comprising any one or more selected from the group consisting of Mg, Al, Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn, Nb, Mo, Pd, Ag, In, Sn, Hf, Ta, W, Pb, and Bi, comprises the steps of: subjecting the faces of the two sheets to be bonded to sputtering treatment with inert gas ions under vacuum such that oxide layers on surface layers remain; temporarily bonding the two sheets by roll pressure bonding; and conducting a thermal treatment to thereby bond the two sheets, and, when Tm1 > Tm2 where Tm1(K) is the melting point of M1 and Tm2(K) is the melting point of M2, the temperature of the thermal treatment is 0.45Tm2 or more and less than 0.45Tm1, provided that the temperature is not more than Tm2.


A surface-treated steel sheet for cans forming a coating of a compound comprising chiefly Zr and containing F, the amount of Zr being 80 to 200 mg/m^(2) and the amount of F being not less than 12 mg/m^(2) in the coating on the surface that becomes the outer surface side of the can. The surface-treated steel sheet is capable of effectively preventing the resin coating from peeling on the outer surface side of the can at dented portions.


Patent
Toyo Kohan Co. | Date: 2016-04-20

There is provided a palladium plate coated material (100) comprising: a base material (10); an underlying alloy layer (20) formed on the base material (10); and a palladium plated layer (30) formed on the underlying alloy layer (20). The palladium plate coated material (100) is characterized in that the underlying alloy layer (20) is formed of an M1-M2-M3 alloy (where M1 is at least one element selected from Ni, Fe, Co, Cu, Zn and Sn, M2 is at least one element selected from Pd, Re, Pt, Rh, Ag and Ru, and M3 is at least one element selected from P and B).


Patent
Toyo Kohan Co. and Toyo Seikan Group Holdings Ltd. | Date: 2016-01-06

A method of producing a surface-treated steel sheet is provided. The method has a step of performing electrolytic treatment thereby to form a layer including a metal-oxygen compound on a surface of a steel sheet. The electrolytic treatment is performed so that the steel sheet is continuously fed into electrolytic treatment baths each including a treatment liquid and an electrode. The treatment liquid contains metal ions. The method is characterized in that: rolls provided for each of the electrolytic treatment baths (a roll for feeding the steel sheet into the electrolytic treatment bath and a roll for feeding the steel sheet out of the electrolytic treatment bath) comprise an energized roll that is electrically connected to a power source for flowing a direct current through the steel sheet and a non-energized roll that is not connected to a power source; and the energized roll is arranged such that, once the metal-oxygen compound has been formed by electrolytic treatment on a surface of the steel sheet to be in contact with the rolls, the metal-oxygen compound and the energized roll are not in contact with each other so as not to generate an arc spot.


Patent
Toyo Kohan Co. | Date: 2016-01-06

A method of producing a surface-treated steel sheet is provided. The surface-treated steel sheet includes a layer that contains a metal oxide. The method is characterized by including: dipping a steel sheet for 0.1 to 10 seconds in a treatment liquid that contains at least fluoride ions and has a pH of 2 to 5; and electrically treating by flowing a direct current between the steel sheet and an electrode in a treatment liquid to form a layer that contains a metal oxide on a surface of the steel sheet. According to the present invention, there can be provided a method of producing a surface-treated steel sheet which can enhance the interfacial adhesion with an organic resin layer when the organic resin layer is formed on the metal oxide layer.


This invention provides a method for forming an oxide layer on a metal substrate, which enables manufacture of an oxide layer with improved crystal orientation in comparison with that of the outermost layer of a metal substrate. The method for forming an oxide layer on a metal substrate 20 via RF magnetron sputtering comprises a step of subjecting the crystal-oriented metal substrate 20 exhibiting a c-axis orientation of 99% on its outermost layer to RF magnetron sputtering while adjusting the angle formed by a perpendicular at a film formation position 20a on the metal substrate 20 and a line from the film formation position 20a to a point 10a at which the perpendicular magnetic flux density is zero on the target 10 located at the position nearest to the film formation position 20a to 15 degrees or less.


Provided is a surface-treated steel sheet for battery containers (100) that is obtained in such a manner that after iron-nickel alloy plating is performed on a steel sheet (10), a thermal treatment is performed and is characterized in that an outermost layer is an iron-nickel alloy layer (20), and the iron-nickel alloy layer (20) has an average crystal size of 1 to 8 m at the outermost surface thereof. The present invention makes it possible to provide the surface-treated steel sheet for battery containers that can suppress the elution of iron inside the battery when being used for a battery container, whereby the service life of the battery can be extended and battery characteristics such as discharge characteristics is improved, and to provide a battery container and a battery that can be obtained using the surface-treated steel sheet for battery containers.


Provided is an alloy plate coated material (100) including a base material (10), and an alloy plate layer (20) which is formed on the base material (10) to constitute an outermost layer and is formed from a M1-M2-M3 alloy (provided that M1 is at least one element selected from Ni, Fe, Co, Cu, Zn and Sn; M2 is at least one element selected from Pd, Re, Pt, Rh, Ag and Ru; and M3 is at least one element selected from P and B), in which the alloy plate layer (20) has a molar ratio of M1 to M2 (M1/M2) of 0.005 to 0.5.

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