Salimov Z.S.,Academy of Sciences of Uzbekistan |
Salimov Z.S.,Tashkent State Engineering University |
Baltaev U.S.,Academy of Sciences of Uzbekistan |
Baltaev U.S.,Tashkent State Engineering University |
And 6 more authors.
Russian Journal of Applied Chemistry | Year: 2011
Results of numerical modeling of the kinetics of reaction of binding of nitrogen at mechanochemical disintegration of water solutions are illustrated. Experimental data of kinetics of more than fifty reactions which in many cases are different from Arrhenius kinetics were used in calculations. It is found that the main channel of nitrogen fixation is the formation of nitrocompounds, but in the presence of small amount of hydrogen the change to the channel of ammonia formation becomes possible. © 2011 Pleiades Publishing, Ltd.