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Chen L.,Beijing Normal University | Wang H.,Shanghai Tianshan High School | Deng X.,Beijing Normal University
Acta Crystallographica Section E: Structure Reports Online | Year: 2014

In the mononuclear TiIVtitle complex, [Ti(C29H33NO2)(C3H6O)2], the TiNO4coordination polyhedron comprises an N-atom and two O-atom donors from the dianionic Schiff base ligand and two O-atom donors from monodentate isopropoxide anions. The stereochemistry is distorted trigonal-bipyramidal with the N-donor in an elongated axial site [Ti - N = 2.2540 (17) Å], the O-donors having normal Ti - O bond lengths [1.7937 (14) Å (axial)-1.8690 (14) Å]. In the crystal, C - H⋯π interactions link molecules into centrosymmetric dimers.


PubMed | Beijing Normal University and Shanghai Tianshan High School
Type: Journal Article | Journal: Acta crystallographica. Section E, Structure reports online | Year: 2014

In the mononuclear Ti(IV) title complex, [Ti(C29H33NO2)(C3H6O)2], the TiNO4 coordination polyhedron comprises an N-atom and two O-atom donors from the dianionic Schiff base ligand and two O-atom donors from monodentate isopropoxide anions. The stereochemistry is distorted trigonal-bipyramidal with the N-donor in an elongated axial site [Ti-N = 2.2540(17)], the O-donors having normal Ti-O bond lengths [1.7937(14) (axial)-1.8690(14)]. In the crystal, C-H inter-actions link mol-ecules into centrosymmetric dimers.

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