Saudi Arabia Basic Industries Corporation

Riyadh, Saudi Arabia

Saudi Arabia Basic Industries Corporation

Riyadh, Saudi Arabia

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Giffin K.A.,University of Ottawa | Pua L.A.,University of Ottawa | Pua L.A.,National University of Singapore | Piotrkowski S.,University of Ottawa | And 6 more authors.
Journal of the American Chemical Society | Year: 2017

Treatment of Ni(0) complexes 1a-e with sub-atmospheric pressures of trifluoroethylene (TrFE) affords hydrofluoronickelacyclopentanes L2Ni(C4F6H2) 2a-e (L = PPh3, P(O-o-tol)3, PPh2Me, PPhMe2, PMe3). Fluorine NMR analysis of 2a-e demonstrates predominant formation of three (of the possible six) isomers upon oxidative cycloaddition of TrFE: the cis and trans head-tail isomers and the trans head-head isomer, where the CHF group is defined as the TrFE “head”. The respective ratios of L2Ni(C4F6H2) isomers are influenced by the nature of L, with smaller phosphines favoring the thermodynamically preferred (from DFT calculations) trans head-head isomer (cf. 50% with PMe3) and the largest affording small amounts of the tail-tail isomers. Lewis and Brønsted acids induce a surprising double C-F bond activation in 2c-d, affording small functionalized hydrofluoroalkenes. Interestingly, varying the acid employed dictates the organic product obtained from the head-tail isomers: BF3·OEt2 is selective for 1,1,2,3-tetrafluorocyclobutene, whereas Me3SiOTf and N,N-dimethylanilinium bromide yield (Z,E)-1,1,3,4-tetrafluorobutadiene as the major fluorinated product. Reaction intermediates were isolated, and possible pathways are discussed. © 2017 American Chemical Society.


News Article | May 18, 2017
Site: www.prnewswire.co.uk

Browse 102 market data Tables and 33 Figures spread through 144 Pages and in-depth TOC on "Heat Resistant Polymers Market" http://www.marketsandmarkets.com/Market-Reports/heat-resistant-polymer-market-237680204.html Early buyers will receive 10% customization on this report. The increase in demand for heat resistant polymers from the transportation and electronics & electrical industries in developing economies is propelling the growth of this market. Transportation segment is one of the fastest-growing segment of the global heat resistant polymers market. The transportation end-use segment is estimated to account for the largest share of the Heat Resistant Polymers Market in 2016, and is projected to be the fastest-growing segment from 2016 to 2021. This growth is mainly attributed to the increasing use of heat resistant polymers in various automotive components and increasing demand of automobiles in Asia-Pacific and North America region. Polyphenylene sulfide type is the fastest-growing segment of the global heat resistant polymers market. The polyphenylene sulfide segment is projected to be the fastest-growing type segment from 2016 to 2021. Polyphenylene sulfide is temperature resistant. In addition, it has superior properties as compared to other polymers, such as superior chemical resistance, flame retardancy, good electrical properties, and high dimensional stability. These properties are expected to boost the demand for polyphenylene sulfide in the automotive and electronics & electrical industries. Asia-Pacific was the largest market for heat resistant polymers in 2016. Asia-Pacific was the largest market for heat resistant polymers in 2016. This increased demand can be attributed to the increasing demand from the transportation end-use industry, which accounts for the largest share in the global market, and growing economies of China and India. Key players operational in the market include Arkema SA (France), E. I. du Pont de Nemours And Company (U.S.), Dongyue Group Ltd. (China), DIC Corporation (Japan), Honeywell International Inc. (U.S.), Parkway Products Inc. (U.S.), Schulman AG (U.S.), Caledonian Ferguson Timpson Ltd (Scotland), Panjin Zhongrun High Performance Polymers Co. Ltd (China), Quadrant EPP Surlon India Ltd (India), Tri-Mack Plastics Manufacturing Corp. (U.S.), Huntsman Corporation (U.S.), PolyOne Corporation (U.S.), BASF SE (Germany), Evonik Industries AG (Germany), Celanese Corporation (U.S.), Solvay S.A. (Belgium), Victrex PLC (U.K.), Saudi Arabia Basic Industries Corporation (SABIC) (Saudi Arabia), Covestro (Germany), The Dow Chemical Company (U.S.), Daikin Industries, Ltd. (Japan), Kuraray Co., Ltd. (Japan), RTP Company, Inc. (U.S.), and Ensinger GmbH (U.K.), among others. High Temperature Plastics Market by Type (Polysulfones, Polyimides, Polyphenylene Sulfide, Fluoropolymers, and Others), by End-Use Industries (Electrical & Electronic, Transportation, Industrial, Medical, and Others) - Global Trends & Forecast to 2019 http://www.marketsandmarkets.com/Market-Reports/high-temperature-plastics-market-1192.html High Performance Plastics Market by Type (Fluoropolymers, High Performance Polyamide, PPS, SP, LCP, AKP, and PI), End-Use Industry (Transportation, Electrical and Electronics, Medical, Industrial), and Region - Global Forecast to 2026 http://www.marketsandmarkets.com/Market-Reports/high-performance-plastic-market-130930168.html MarketsandMarkets™ provides quantified B2B research on 30,000 high growth niche opportunities/threats which will impact 70% to 80% of worldwide companies' revenues. Currently servicing 5000 customers worldwide including 80% of global Fortune 1000 companies as clients. Almost 75,000 top officers across eight industries worldwide approach MarketsandMarkets™ for their painpoints around revenues decisions. Our 850 fulltime analyst and SMEs at MarketsandMarkets™ are tracking global high growth markets following the "Growth Engagement Model - GEM". The GEM aims at proactive collaboration with the clients to identify new opportunities, identify most important customers, write "Attack, avoid and defend" strategies, identify sources of incremental revenues for both the company and its competitors. MarketsandMarkets™ now coming up with 1,500 MicroQuadrants (Positioning top players across leaders, emerging companies, innovators, strategic players) annually in high growth emerging segments. MarketsandMarkets™ is determined to benefit more than 10,000 companies this year for their revenue planning and help them take their innovations/disruptions early to the market by providing them research ahead of the curve. MarketsandMarkets' flagship competitive intelligence and market research platform, "RT" connects over 200,000 markets and entire value chains for deeper understanding of the unmet insights along with market sizing and forecasts of niche markets. Visit MarketsandMarkets Blog @ http://www.marketsandmarketsblog.com/market-reports/chemical Connect with us on LinkedIn @ http://www.linkedin.com/company/marketsandmarkets


News Article | May 18, 2017
Site: www.prnewswire.com

Browse 102 market data Tables and 33 Figures spread through 144 Pages and in-depth TOC on "Heat Resistant Polymers Market" http://www.marketsandmarkets.com/Market-Reports/heat-resistant-polymer-market-237680204.html Early buyers will receive 10% customization on this report. The increase in demand for heat resistant polymers from the transportation and electronics & electrical industries in developing economies is propelling the growth of this market. Transportation segment is one of the fastest-growing segment of the global heat resistant polymers market. The transportation end-use segment is estimated to account for the largest share of the Heat Resistant Polymers Market in 2016, and is projected to be the fastest-growing segment from 2016 to 2021. This growth is mainly attributed to the increasing use of heat resistant polymers in various automotive components and increasing demand of automobiles in Asia-Pacific and North America region. Polyphenylene sulfide type is the fastest-growing segment of the global heat resistant polymers market. The polyphenylene sulfide segment is projected to be the fastest-growing type segment from 2016 to 2021. Polyphenylene sulfide is temperature resistant. In addition, it has superior properties as compared to other polymers, such as superior chemical resistance, flame retardancy, good electrical properties, and high dimensional stability. These properties are expected to boost the demand for polyphenylene sulfide in the automotive and electronics & electrical industries. Asia-Pacific was the largest market for heat resistant polymers in 2016. Asia-Pacific was the largest market for heat resistant polymers in 2016. This increased demand can be attributed to the increasing demand from the transportation end-use industry, which accounts for the largest share in the global market, and growing economies of China and India. Key players operational in the market include Arkema SA (France), E. I. du Pont de Nemours And Company (U.S.), Dongyue Group Ltd. (China), DIC Corporation (Japan), Honeywell International Inc. (U.S.), Parkway Products Inc. (U.S.), Schulman AG (U.S.), Caledonian Ferguson Timpson Ltd (Scotland), Panjin Zhongrun High Performance Polymers Co. Ltd (China), Quadrant EPP Surlon India Ltd (India), Tri-Mack Plastics Manufacturing Corp. (U.S.), Huntsman Corporation (U.S.), PolyOne Corporation (U.S.), BASF SE (Germany), Evonik Industries AG (Germany), Celanese Corporation (U.S.), Solvay S.A. (Belgium), Victrex PLC (U.K.), Saudi Arabia Basic Industries Corporation (SABIC) (Saudi Arabia), Covestro (Germany), The Dow Chemical Company (U.S.), Daikin Industries, Ltd. (Japan), Kuraray Co., Ltd. (Japan), RTP Company, Inc. (U.S.), and Ensinger GmbH (U.K.), among others. High Temperature Plastics Market by Type (Polysulfones, Polyimides, Polyphenylene Sulfide, Fluoropolymers, and Others), by End-Use Industries (Electrical & Electronic, Transportation, Industrial, Medical, and Others) - Global Trends & Forecast to 2019 http://www.marketsandmarkets.com/Market-Reports/high-temperature-plastics-market-1192.html High Performance Plastics Market by Type (Fluoropolymers, High Performance Polyamide, PPS, SP, LCP, AKP, and PI), End-Use Industry (Transportation, Electrical and Electronics, Medical, Industrial), and Region - Global Forecast to 2026 http://www.marketsandmarkets.com/Market-Reports/high-performance-plastic-market-130930168.html MarketsandMarkets™ provides quantified B2B research on 30,000 high growth niche opportunities/threats which will impact 70% to 80% of worldwide companies' revenues. Currently servicing 5000 customers worldwide including 80% of global Fortune 1000 companies as clients. Almost 75,000 top officers across eight industries worldwide approach MarketsandMarkets™ for their painpoints around revenues decisions. Our 850 fulltime analyst and SMEs at MarketsandMarkets™ are tracking global high growth markets following the "Growth Engagement Model - GEM". The GEM aims at proactive collaboration with the clients to identify new opportunities, identify most important customers, write "Attack, avoid and defend" strategies, identify sources of incremental revenues for both the company and its competitors. MarketsandMarkets™ now coming up with 1,500 MicroQuadrants (Positioning top players across leaders, emerging companies, innovators, strategic players) annually in high growth emerging segments. MarketsandMarkets™ is determined to benefit more than 10,000 companies this year for their revenue planning and help them take their innovations/disruptions early to the market by providing them research ahead of the curve. MarketsandMarkets' flagship competitive intelligence and market research platform, "RT" connects over 200,000 markets and entire value chains for deeper understanding of the unmet insights along with market sizing and forecasts of niche markets. Visit MarketsandMarkets Blog @ http://www.marketsandmarketsblog.com/market-reports/chemical Connect with us on LinkedIn @ http://www.linkedin.com/company/marketsandmarkets

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