Time filter

Source Type

Takjoo R.,Islamic Azad University at Mashhad | Takjoo R.,Islamic Azad University at Shirvan | Yazdanbakhsh M.,Ferdowsi University of Mashhad | Aghaei Kaju A.,Research Institute of science and Food Technology | Chen Y.,Northeast Normal University
Chinese Journal of Chemistry | Year: 2010

A new mixed ligand palladium(II) complex with bidentate NS-donor chelate, [PdCl(PPh3)L] (L: S-allyl β-N-(benzylidene)dithiocarbazate), has been prepared and characterized using single crystal X-ray diffraction and spectroscopic (electronic, IR, 1H NMR and 13C NMR) techniques. The shorter Pd-P bond distance, 2.255(7) Å, than the sum of the single bond radii for palladium and phosphorus (2.41Å), showed partial double bond character. Visualizing and exploring the crystal structure using Hirshfeld surface analysis showed the presence of π···π, N···π, C-H···π, Cl···H and weak C-H···S interactions as most important intermolecular interactions in the crystal lattice, which are responsible to extension of the supramolecular network of the compound and stabilization of the crystal structure. © 2010 SIOC, CAS, Shanghai, & WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Source

Discover hidden collaborations