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Lee D.S.,PolyU Shenzhen Research Institute SZRI | Choy P.Y.,PolyU Shenzhen Research Institute SZRI | So C.M.,PolyU Shenzhen Research Institute SZRI | Wang J.,PolyU Shenzhen Research Institute SZRI | And 4 more authors.
RSC Advances | Year: 2012

This study reports the first general Pd-catalyzed direct arylation of polyfluoroarenes with aryl tosylates/mesylates. A wide range of polyfluoroarenes can be coupled with both aryl tosylates and mesylates under relatively mild reaction conditions (90 °C, in the presence of a weak base KOAc, without any additional acid additives). Moreover, a one-pot sequential C-H bond functionalization/C-N bond coupling has been successfully accomplished by employing one single Pd/CM-phos catalyst system. © 2012 The Royal Society of Chemistry. Source

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