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Udvardy A.,Debrecen University | Benyei A.C.,Debrecen University | Juhasz P.,Debrecen University | Joo F.,Debrecen University | And 2 more authors.
Polyhedron | Year: 2013

Ion pairs consisting of N-substituted derivatives of 1,3,5-triaza-7- phosphaadamantane (pta-R; R = benzyl, butyl, hexyl) as cations and monosulfonated triphenylphosphine (mtppms) as anion were synthesized and characterized (including X-ray diffraction, too). These ion pairs act as bidentate phosphorus ligands in reactions with [(η6-C 10H14)RuCl2]2, yielding mononuclear or dinuclear half sandwich Ru(II) complexes. Bisphosphine 3 of good water-solubility was synthesized in reaction of pta with 1,4-bis(chloromethyl) benzene and used for the synthesis of the water-soluble dinuclear complex [{(η6-C10H14)- RuCl2} 2(μ-3)]Cl2. © 2013 Elsevier Ltd. All rights reserved.

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