Mta Of Research Group Of Homogeneous Catalysis And Reaction Mechanisms

Debrecen, Hungary

Mta Of Research Group Of Homogeneous Catalysis And Reaction Mechanisms

Debrecen, Hungary

Time filter

Source Type

Udvardy A.,Debrecen University | Benyei A.C.,Debrecen University | Juhasz P.,Debrecen University | Joo F.,Debrecen University | And 2 more authors.
Polyhedron | Year: 2013

Ion pairs consisting of N-substituted derivatives of 1,3,5-triaza-7- phosphaadamantane (pta-R; R = benzyl, butyl, hexyl) as cations and monosulfonated triphenylphosphine (mtppms) as anion were synthesized and characterized (including X-ray diffraction, too). These ion pairs act as bidentate phosphorus ligands in reactions with [(η6-C 10H14)RuCl2]2, yielding mononuclear or dinuclear half sandwich Ru(II) complexes. Bisphosphine 3 of good water-solubility was synthesized in reaction of pta with 1,4-bis(chloromethyl) benzene and used for the synthesis of the water-soluble dinuclear complex [{(η6-C10H14)- RuCl2} 2(μ-3)]Cl2. © 2013 Elsevier Ltd. All rights reserved.

Loading Mta Of Research Group Of Homogeneous Catalysis And Reaction Mechanisms collaborators
Loading Mta Of Research Group Of Homogeneous Catalysis And Reaction Mechanisms collaborators