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Li C.,CAS Shanghai Institute of Organic Chemistry | Xiao G.,CAS Shanghai Institute of Organic Chemistry | Zhao Q.,CAS Shanghai Institute of Organic Chemistry | Liu H.,Mettler Toledo International Trading Co. | And 2 more authors.
Organic Chemistry Frontiers | Year: 2014

Efficient sterically demanding aryl-alkyl Suzuki-Miyaura coupling between di-ortho-substituted aryl halides and secondary alkylboronic acids has been achieved with a Pd-AntPhos catalyst that has shown high reactivity and a broad substrate scope with unprecedented steric hindrance. The methodology has facilitated the synthesis of molecular gears such as by cross-coupling. © 2014 the Partner Organisations. Source

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