Chieregato A.,Polytechnic University of Valencia |
Chieregato A.,Materials Universitdi Bologna |
Soriano M.D.,Polytechnic University of Valencia |
Garcia Gonzalez E.,Complutense University of Madrid |
And 6 more authors.
ChemSusChem | Year: 2015
Glycerol surplus from biodiesel synthesis still represents a major problem in the biofuel production chain. Meanwhile, those in the acrylic acid market are looking for new processes that are able to offer viable alternatives to propylene-based production. Therefore, acrylic acid synthesis from glycerol could be an effective solution to both issues. Among the viable routes, one-pot synthesis theoretically represents the most efficient process, but it is also highly challenging from the catalyst design standpoint. A new class of complex W-; Mo-V mixed-oxide catalysts, which are strongly related to the hexagonal tungsten bronze structure, able to directly convert glycerol into acrylic acid with yields of up to 51% are reported. ©2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.