Mor G.K.,Materials Research Institute, LLC |
Basham J.,Materials Research Institute, LLC |
Paulose M.,Materials Research Institute, LLC |
Kim S.,Pennsylvania State University |
And 4 more authors.
Nano Letters | Year: 2010
Solid-state dye-sensitized solar cells (SS-DSCs) offer the potential to make low cost solar power a reality, however their photoconversion efficiency must first be increased. The dyes used are commonly narrow band with high absorption coefficients, while conventional photovoltaic operation requires proper band edge alignment significantly limiting the dyes and charge transporting materials that can be used in combination. We demonstrate a significant enhancement in the light harvesting and photocurrent generation of SS-DSCs due to Förster resonance energy transfer (FRET). TiO2 nanotube array films are sensitized with red/near IR absorbing SQ-1 acceptor dye, subsequently intercalated with Spiro-OMeTAD blended with a visible light absorbing DCM-pyran donor dye. The calculated Förster radius is 6.1 nm. The donor molecules contribute a FRET-based maximum IPCE of 25% with a corresponding excitation transfer efficiency of approximately 67.5%. © 2010 American Chemical Society. Source
Agency: Department of Defense | Branch: Air Force | Program: SBIR | Phase: Phase I | Award Amount: 99.94K | Year: 2007
This Phase I program will use metallized carbon nanofibers to develop a class of electrically conductive structural adhesives and bolt hole fillers to improve the electrical and thermal transport properties of organic matrix composite structures. Metallized carbon nanofibers have the beneficial large aspect ratio of the carbon nanofiber and high electrical conductivity of the metal. They can confer significant electrical conductivity to polymer resins at moderate concentrations. In Phase I, MRI will produce silver- and copper-metallized carbon nanofibers of varying metal compositions. The metallized carbon nanofibers will be integrated with structural adhesive resins to formulate the electrically conductive structural adhesives and bolt hole fillers. An initial screening test will be employed to identify the most promising candidate materials. More elaborate electrical, thermal, mechanical, and lightning strike characterizations will be carried out on samples of selected candidate materials to demonstrate the feasibility of the proposed technology.
Agency: Department of Defense | Branch: Air Force | Program: SBIR | Phase: Phase II | Award Amount: 849.81K | Year: 2003
This SBIR Phase II program will continue research and development of carbon nanotubes for conductive polymer hybrids. The objective is to develop a multifunctional composite material with significant thermal and electrical conductivity for shielding,electrostatic discharge, thermal management, and energy storage and conversion applications. The approach to the high conductivity is via establishing a carbon nanotube network with effective inter- as well as intra-tube transport property in the polymermatrix. Feasibility of this approach was demonstrated in Phase I program. Resulting polymer-nanotube hybrids exhibited electrical conductivity above 200 S/cm with 15 vol.% loading of nanotubes. They also achieved substantially enhanced thermalconductivity. Proposed Phase II efforts include optimizing the processing conditions and developing a process for manufacturing the conductive polymer hybrids in pilot scales. The polymer hybrid material will also be processed into shaped articles usingconventional extrusion and molding techniques. Their thermal, mechanical, electrical, and morphological properties will be characterized to confirm their processing, structure and property relationships.
Agency: Department of Defense | Branch: Air Force | Program: SBIR | Phase: Phase I | Award Amount: 100.00K | Year: 2002
"This SBIR Phase I research program will develop a processing scheme for producing polymer-nanotube hybrids with significant electrical and thermal conductivity for multifunctional applications. Using carbon nanotubes to impart transport properties toorganic polymers requires the nanotubes to form a conductive network in the polymer matrix. To obtain high electrical and thermal conductivity, the Phase I research will focus on achieving uniform dispersion of the choice carbon nanotubes, maintainingtheir large aspect ratio during processing, and enhancing inter-tube charge transport properties. The processing scheme will be applicable to a wide range of polymers, including thermoplstic, thermosetting, and high-temperature aromatic heterocyclicpolymers. The resulting conductive polymer-nanotube hybrid material will have applications in shielding, thermal management, electrostatic discharge, corrosion protection, and electro-optical devices such as photovoltaics. The polymer-nanotube hybrids canbe tailored with a wide range of thermal, mechanical, and electrical properties for multifunctional applications in coatings, caulks, sealant, adhesives, fibers, films, sheets, tubes, and large structural components. Potential commercial applications forthe conductive nanocomposite material include shielding, charge dissipation, electrostatic painting, corrosion prevention, thermal management, mechanical reinforcement, and electro-optical devi
Chiadini F.,University of Salerno |
Fiumara V.,University of Basilicata |
Scaglione A.,University of Salerno |
Pulsifer D.P.,Pennsylvania State University |
And 4 more authors.
Optics and Photonics News | Year: 2011
Researchers are looking to the compound eyes of insects as a model for developing their unique approach to harvesting sunlight. Each compound eye comprises several cylindrical eyelets called ommatidia that are arrayed on a curved surface. Light propagating along the axis of an ommatidium is collected to form an image, but light propagating in other directions and reaching an ommatidium is absorbed by its dark side wall. The first phase requires the numerical simulation of light interacting with the air-silicon interface. A simplified two-dimensional bioinspired texturing of the exposed face was considered as the first step of this phase. Results indicated that the bioinspired textured solar cell exhibits light-coupling efficiency. A Nano4 technique has been developed to manufacture multiple high-fidelity replicas of a single biotemplate. The technique can produce multiple replicas simultaneously of multiple biotemplates. Source