Shishilov O.N.,Leninsky Pr. 31 |
Podobedov R.E.,Leninsky Pr. 31 |
Rezinkova Y.N.,Leninsky Pr. 31 |
Churakov A.V.,Leninsky Pr. 31 |
Efimenko I.A.,Leninsky Pr. 31
Dalton Transactions | Year: 2013
Reactions of Pd4(NO)4(CF3CO 2)4 with olefins were studied, this Pd-cluster was shown to promote the oxidation of olefins into ketones, which were found as ketonyl ligands in complex products of the reaction; 6-nuclear palladium clusters with carboxylate and ketonyl ligands Pd6(μ-Cl)x(μ-CF 3CO2)4(μ,κ2-CH 2C(O)CMe3)6-x were characterized by XRD analysis. © The Royal Society of Chemistry 2013.