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Bernas U.,Warsaw University of Technology | Bernas U.,Laboratory of Technological Processes | Hajmowicz H.,Warsaw University of Technology | Hajmowicz H.,Laboratory of Technological Processes | And 7 more authors.
Arkivoc | Year: 2010

Practical acylation of unprotected tartaric acid 1 by acyl chlorides to the corresponding monoacyltartaric acids 2 has been shown. Several unusual cases in the acylation of 1 are observed; it has been found that two routes of acylation are possible. In the benzoylation of 1, in addition to the expected products, the formation of a previously undescribed monobenzoyltartaric anhydride 7a is reported. An unusual DME cleavage during the course of acylation was also observed. © ARKAT USA, Inc. Source

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