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Wu N.,Laboratory of Chemical Genomics | Wu N.,CAS Beijing National Laboratory for Molecular | Deng L.,Laboratory of Chemical Genomics | Deng L.,CAS Beijing National Laboratory for Molecular | And 8 more authors.
Chemistry - An Asian Journal | Year: 2013

Which way? Palladium thiourea catalyzed Pauson-Khand reaction of norbornene with substituted alkynoates to afford selectively either α-carboxylated adducts or β-carboxylated adducts with the reverse regioselectivity has been demonstrated for the first time. Control of the regioselectivity in this transformation is governed by the addition of LiCl. A mechanistic interpretation to account for this observed regioselectivity is presented. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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