Tripathi C.S.P.,Laboratorium voor Akoestiek en Thermische Fysica |
Losada-Perez P.,Laboratorium voor Akoestiek en Thermische Fysica |
Leys J.,Laboratorium voor Akoestiek en Thermische Fysica |
Cordoyiannis G.,Jozef Stefan Institute |
And 3 more authors.
European Physical Journal E | Year: 2012
The high-resolution adiabatic scanning calorimetric technique has been used to investigate the nematic-smectic A transition (N-SmA) in binary mixtures of the non-smectogenic liquid crystal heptyloxycyanobiphenyl (7OCB) and heptane, exhibiting a so-called injected smectic A phase. With the exception of a mixture with the lowest heptane mole fraction for which only an upper limit of 0.2 ± 0.2Jkg-1 for a possible latent heat could be obtained, for all other mixtures finite latent heats were obtained. The mole fraction dependence of the latent heat could be well fitted with a crossover function consistent with a mean-field free energy expression with a non-zero cubic term arising from the Halperin-Lubensky-Ma (HLM) coupling between the SmA order parameter and the orientational director fluctuations. The mole fraction dependence of the heat capacity effective critical exponents is similar to that observed in mixtures of the two liquid crystals octyloxycyanobiphenyl (8OCB) and nonylcyanobiphenyl (9OCB). The thermal behavior observed along the N-SmA phase transition line yields further strong evidence for the HLM coupling effect.© Springer-Verlag 2012.