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Alcantara E.,Institute Quimica Unam | Sharma P.,Institute Quimica Unam | Perez D.,Institute Quimica Unam | Cabrera A.,Institute Quimica Unam | And 4 more authors.
Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry | Year: 2012

Bismuthine Ph 2BiFc containing the pendant arm 2-(Me 2NCH 2)-(1) on ferrocenyl ring was synthesized, and reaction of (1) with CH 3I was carried out to obtain the monoammonium salt {[2-(Me 3N +CH 2)Fc]}BiPh 2[I]-(2). Molecular structures of bismuthines (1) and (2) have been determined by X-ray crystallography. Compound (1) does not show hypervalent Bi-N interaction. New 1,2-disubstituted ferrocenyl bismuthines have been characterized by various physicochemical techniques. © 2012 Taylor amp; Francis Group, LLC.

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