Institute Catalisis y Petroleoquimica ICP

Madrid, Spain

Institute Catalisis y Petroleoquimica ICP

Madrid, Spain
Time filter
Source Type

Sanchez-Sanchez M.,Institute Catalisis y Petroleoquimica ICP | Romero A.A.,Institute Catalisis y Petroleoquimica ICP | Pinilla-Herrero I.,Institute Catalisis y Petroleoquimica ICP | Sastre E.,Institute Catalisis y Petroleoquimica ICP
Catalysis Today | Year: 2017

This work reports the ionothermal synthesis of SAPO-34 material, which is the per-excellence catalyst in the methanol-to-olefins (MTO) process. The direct addition of Si sources to the aluminophosphate and ionic liquid (1-ethyl-3-methyl imidazolium) mixture gave rise to the undesired AEL-structured materials. Therefore, some other strategies were necessary to apply. In particular, two unexplored strategies have been developed: (i) the addition of further heteroatom ions able to direct CHA materials, V ions being particularly efficient; and (ii) to carry out the synthesis in open systems rather than in autoclaves under autogenous pressure. Interestingly, the combination of both strategies led to V4+-free SAPO-34 samples, so any Brönsted acidity of the samples should be assigned to the incorporated Si atoms. These materials, far from being conventional SAPO-34, have triclinic CHA structure, which provides some structural singularities and have not been tested as catalysts in the MTO reaction yet. Despite their conversion level achieved was lower than that given by conventional SAPO-34, probably because of the scarce optimization of the physicochemical properties of the material, the selectivity towards the different olefins is interestingly different, favoring C4 olefins at the expense of ethylene and propylene. © 2017 Elsevier B.V.

Guesh K.,Aksum University | Caiuby C.A.D.,Institute Catalisis y Petroleoquimica ICP | Mayoral A.,University of Zaragoza | Diaz-Garcia M.,Institute Catalisis y Petroleoquimica ICP | And 2 more authors.
Crystal Growth and Design | Year: 2017

The real industrial establishment of metal-organic frameworks (MOFs) requires significant advances in economic and chemical sustainability. This work describes a novel and simple method to prepare one of the most widely studied MOF materials, i.e., MIL-100(Fe), which significantly improves the sustainability of the conventional process in several aspects. This MOF material is prepared (i) at room temperature (instead of 150 °C used in the conventional method), (ii) after a few hours (instead of 6 days), (iii) in the absence of any inorganic corrosive acid (significant amounts of HF and HNO3 are used in the conventional method), and (iv) it is washed at room temperature (unlike the washing at 80 °C for 3 h). Interestingly, the only difference in the preparation method of MIL-100(Fe) compared with that of semiamorphous Fe-BTC (MOF material commercialized as Basolite F300 having the same metal and linker, and which can be also prepared under similar sustainable conditions) is to start from Fe(II) or Fe(III) sources, respectively, which opens certain versatility options in the room temperature synthesis procedures of MOF materials. The prepared samples were characterized using X-ray diffraction, thermogravimetric analysis, N2 adsorption/desorption isotherms, Cs-aberration corrected scanning transmission electron microscopy, and UV-vis diffuse reflectance spectroscopy. These two room-temperature-made Fe-BTC materials were tested in the industrially demanded photocatalytic degradation of methyl orange under both ultraviolet and solar light radiation. MIL-100(Fe) was a very active photocatalyst in comparison with its homologue. That difference was mainly attributed to the presence of larger cavities within its structure. © 2017 American Chemical Society.

Canalejas-Tejero V.,Technical University of Madrid | Carrasco S.,Complutense University of Madrid | Navarro-Villoslada F.,Complutense University of Madrid | Garcia Fierro J.L.,Institute Catalisis y Petroleoquimica ICP | And 3 more authors.
Journal of Materials Chemistry C | Year: 2013

A non-chemically amplified negative-tone electron-beam resist with an extremely high sensitivity is presented in this work. The resist, poly(2-hydroxyethyl methacrylate-co-2-methacrylamidoethyl methacrylate) (P(HEMA-co-MAAEMA)), has been synthesized using free radical polymerization of 2-hydroxyethyl methacrylate and 2-aminoethyl methacrylate, and exhibits a crosslinking threshold dose as low as 0.5 μC cm-2. Exposed resist patterns show good adherence to silicon substrates without the assistance of adhesion promoters or thermal treatments and are shown to be adequate for use as a mask for both wet and dry etching of Si. A low contrast value of 1.2 has been measured, indicating that the synthesized polymeric mixture is particularly suitable for achieving grey (3D) lithography. Other relevant properties of the new e-beam resist are optical transparency, visible photoluminescence when crosslinked at low electronic doses, and dose-dependent dual-tone behaviour. This journal is © The Royal Society of Chemistry 2013.

Rasmussen S.B.,Institute Catalisis y Petroleoquimica ICP | Banares M.A.,Institute Catalisis y Petroleoquimica ICP | Bazin P.,National Engineering School of Caen | Due-Hansen J.,Technical University of Denmark | And 2 more authors.
Physical Chemistry Chemical Physics | Year: 2012

A monolithic vanadia-titania based catalyst has been subjected to studies with in situ FTIR spectroscopy coupled with mass spectrometry, during the SCR (Selective Catalytic Reduction) reaction. A device based on a transmission reactor cell for monolithic samples was constructed, dedicated to the study of surface species during reaction. After analysing the steady state SCR activity under industrially relevant conditions, NH 3 chemisorption phenomena as a function of temperature and the subsequent SCR reaction of NO + O 2 with chemisorbed ammonia and ammonium ion species were also investigated. The observations reported here serve as a demonstration of the great potential for the application of operando spectroscopy on monolithic systems. This cross disciplinary approach aims to identify reaction pathways, active sites, intermediate- and spectator-species for catalytic reactions under truly industrial conditions in a shaped monolithic catalyst based on monitoring chemical profiles along its channels. In particular, by demonstrating the feasibility of the approach using the technically challenging operando transmission FTIR spectroscopy methodology, we foresee easy future adaption of this approach with other surface or bulk sensitive techniques, e.g. Raman and UV-vis spectroscopy. © 2012 the Owner Societies.

Rasmussen S.B.,Institute Catalisis y Petroleoquimica ICP | Rasmussen S.B.,Technical University of Denmark | Perez-Ferreras S.,Institute Catalisis y Petroleoquimica ICP | Banares M.A.,Institute Catalisis y Petroleoquimica ICP | And 2 more authors.
ACS Catalysis | Year: 2013

Porosity is a factor affecting catalyst efficiency in pelletized form. This implies that care should be taken with uncritically relating activity measurements from transmission operando FTIR to final catalyst performance. If the pelletizing pressure is excessive, a destruction of the pore structure of, for example, support oxides might take place, which in turn affects the pore size distribution and the porosity of the catalyst, leading to the observation of lower activity values due to decreased catalyst efficiency. This phenomenon can also apply to conventional activity measurements, in the cases that pelletizing and recrushing of samples are performed to obtain adequate particle size fractions for the catalytic bed. A case study of an operando investigation of a V2O5-WO3/TiO2-sepiolite catalyst is used as an example, and simple calculations of the influence of catalyst activity and internal pore diffusion properties are considered in this paper for the evaluation of catalyst performance in, for example, operando reactors. Thus, it is demonstrated that with a pelletizing pressure of <1-2 ton/cm2, the pore structure is only negligibly altered, and small deteriorations of estimated catalyst efficiencies are observed for first-order kinetic constants lower than 100 mL/gs. However, if the operando study deals with highly active catalysts, it is necessary to consider efficiency losses. A simple procedure for evaluating efficiencies based on pellet dimensions and solid phase characteristics is proposed. The Thiele modulus is directly proportional to the thickness of the pellet, and, thus, inversely related to the catalyst efficiency. As a rule of thumb, we found that for catalytic constants below 100 mL/gs, the maximum thickness of the pellet pressed at 2 tons/cm 2 has to be as low as 80 μm to exhibit catalyst efficiencies above 90%. For catalysts with k' = 10 mL/gs, the value is 260 μm. This strongly underlines the importance of taking internal diffusion limitations into account when working with highly active catalysts. © 2012 American Chemical Society.

Patino J.,CSIC - Institute of Materials Science | Gutierrez M.C.,CSIC - Institute of Materials Science | Carriazo D.,CSIC - Institute of Materials Science | Carriazo D.,Ikerbasque | And 4 more authors.
Journal of Materials Chemistry A | Year: 2014

Deep eutectic solvents (DESs) composed of resorcinol, 3-hydroxypyridine and tetraethylammonium bromide were used for the synthesis of hierarchical nitrogen-doped carbon molecular sieves. DESs played multiple roles in the synthetic process, as the liquid medium that ensures reagent homogenization, the structure-directing agent responsible for the achievement of the hierarchical structure, and the source of carbon and nitrogen for the solid sorbent obtained after carbonization. Thus, the synthesis offers an economy of reagents that emphasizes the green nature and low cost of conventional polycondensation. Interestingly, while macropores facilitated mass transport and access to the surface area, the combination of the molecular sieve structure and nitrogen functionalization provided, respectively, excellent CO2 adsorption capacities of up to 3.7 mmol g-1, and outstanding CO 2-N2 selectivities of up to 14.4 from single component gas data. Nonetheless, the CO2-N2 selectivity in the Henry law regime-representative of post-combustion flue-gas streams-of some of our carbons was particularly remarkable (e.g. 96), comparable to or even higher than those described for most recent carbons, and only surpassed by those of certain zeolites. This journal is © the Partner Organisations 2014.

Lopez-Salas N.,CSIC - Institute of Materials Science | Gutierrez M.C.,CSIC - Institute of Materials Science | Ania C.O.,CSIC - National Coal Institute | Fierro J.L.G.,Institute Catalisis y Petroleoquimica ICP | And 2 more authors.
Journal of Materials Chemistry A | Year: 2014

Since the seminal work by Pekala in 1989, polycondensation of phenol derivatives with formaldehyde and subsequent carbonization has been one of the most used procedures for preparation of porous carbons. Nitrogen-doped carbons have also been obtained through this approach only by using nitrogen-rich precursors. The list of the most commonly used nitrogen-rich precursors includes melamine, urea, 3-hydroxypyridine, 3-aminophenol and lysine, and despite a few of them can be used in a single fashion, they typically need to be co-condensed with a second precursor. Nitrogen-rich precursors different from these ones have been used rarely because their molecular structure does not favor the nucleophilic substitution through which polycondensation takes place-e.g. p-nitrophenol. This is by no means a trivial issue because, on the one hand, these precursors cannot form a cross-linked network by themselves, and on the other hand, it may be difficult to encompass their different reaction kinetics when combined with more reactive precursors. This is also the situation for other precursors with an amphiphilic molecular structure that could be of interest to control the structure of the resulting porous carbons-e.g. 4-hexylresorcinol. In this work, we have used deep eutectic solvents composed of resorcinol, 4-hexylresorcinol, p-nitrophenol and choline chloride for the preparation of nitrogen-doped carbon monoliths with a hierarchical porous structure. Carbon conversions ranged from 64 to 50%-depending on the carbonization temperature-despite using three different carbon precursors for co-condensation and two of them were uncommon. The nitrogen content ranged from 4.9 to 3.0 wt%, revealing an excellent nitrogen-doping efficiency for p-nitrophenol when used in the form of DES. Finally, the use of 4-hexylresorcinol controlled the formation of a narrow microporosity that, in combination with the nitrogen functionalities, provided a remarkable CO2-sorption capability to the resulting carbons. This journal is © the Partner Organisations 2014.

Rosmaninho M.G.,Federal University of Minas Gerais | Tristao J.C.,Federal University of Minas Gerais | Moura F.C.C.,Federal University of Minas Gerais | Lago R.M.,Federal University of Minas Gerais | And 2 more authors.
Analytical and Bioanalytical Chemistry | Year: 2010

A series of bulk and Al2O3-supported perovskite oxides of the type LaMn1 - x - y Fe x Mo y O3 (x = 0.00-0.90 and y = 0.00-0.09) were synthesized by the citric acid complexation-gelation method followed by annealing in air at 800 °C. For all samples, the local environment and the chemical state and concentration of surface species were determined. Mössbauer spectra revealed the only presence of octahedral Fe3+ ions dispersed in the perovskite structure, however well-crystallized together with a poorly crystalline LaFeO3 phases were detected for larger substitutions (x = 0.90). A similar picture was obtained for Mo-loaded (y = 0.02 and 0.05) samples but a new phase most likely related to Fe3+ ions dispersed aside from the perovskite structure was found for larger substitutions (y = 0.09). Together with these structures, supported samples showed the presence of LaFeO 3 nanoparticles. Finally, photoelectron spectroscopy indicated that the chemical state and composition of the samples in the surface region (2-3 nm) approaches that of the bulk. For the unsupported substituted samples, iron (and molybdenum) enters into the perovskite structure while manganese tends to be slightly segregated. Moreover, in supported perovskites, a fraction of Mo and La atoms interact with the alumina surface. All these oxides were active in methane combustion and best performance was recorded for the Fe-rich composition (x = 0.9) in which both Mn3+ and Mo3+ ions were in the same proportion (y = 0.05). © 2009 Springer-Verlag.

Hamdan A.A.,Aix - Marseille University | Burlat B.,Aix - Marseille University | Gutierrez-Sanz O.,Institute Catalisis y Petroleoquimica ICP | Liebgott P.-P.,Aix - Marseille University | And 6 more authors.
Nature Chemical Biology | Year: 2013

We studied the mechanism of aerobic inactivation of Desulfovibrio fructosovorans nickel-iron (NiFe) hydrogenase by quantitatively examining the results of electrochemistry, EPR and FTIR experiments. They suggest that, contrary to the commonly accepted mechanism, the attacking O2 is not incorporated as an active site ligand but, rather, acts as an electron acceptor. Our findings offer new ways toward the understanding of O2 inactivation and O2 tolerance in NiFe hydrogenases. © 2013 Nature America, Inc. All rights reserved.

Mikolajska E.,Institute Catalisis y Petroleoquimica ICP | Rasmussen S.B.,Institute Catalisis y Petroleoquimica ICP | Lewandowska A.E.,Institute Catalisis y Petroleoquimica ICP | Banares M.A.,Institute Catalisis y Petroleoquimica ICP
Physical Chemistry Chemical Physics | Year: 2012

Alumina-supported VPO materials are efficient catalysts for acrylonitrile production by the propane ammoxidation reaction. In order to understand the structure-activity relationship and the nature of active sites, operando Raman-GC analyses follow the states of vanadium and phosphorous species on an alumina support during ammoxidation. These oxides were supported on γ-alumina by incipient wetness impregnation at a total V + P loading of two monolayers, which led to incipient formation of nanoscaled VPO crystallites possessing a high surface-to-volume ratio. Since catalysis occurs at the catalyst surface, which is related to the surface and outermost layers, this approach allows studying surface species phase transformations near the surface, and relates changes in activity and selectivity to variations in composition and structure. Dispersed surface V 5+ species appear selective to acetonitrile and V 4+ species would promote selectivity to acrylonitrile. This study suggests that V 3+ is probably involved in redox processes during propane ammoxidation and that the balance between these vanadium species would be determined by activation process. © 2012 the Owner Societies.

Loading Institute Catalisis y Petroleoquimica ICP collaborators
Loading Institute Catalisis y Petroleoquimica ICP collaborators