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Chen L.,Sichuan University | He Y.,Sichuan University | Chai S.,Guangdong Shengyi Technology Ltd Corporation | Qiang H.,Sichuan University | And 2 more authors.
Nanoscale | Year: 2013

Two-dimensional graphene and graphene-based materials have attracted tremendous interest, hence much attention has been drawn to exploring and applying their exceptional characteristics and properties. Integration of graphene sheets into macroscopic fibers is a very important way for their application and has received increasing interest. In this study, neat and macroscopic graphene fibers were continuously spun from graphene oxide (GO) suspensions followed by chemical reduction. By varying wet-spinning conditions, a series of graphene fibers were prepared, then, the structural features, mechanical and electrical performances of the fibers were investigated. We found the orientation of graphene sheets, the interaction between inter-fiber graphene sheets and the defects in the fibers have a pronounced effect on the properties of the fibers. Graphene fibers with excellent mechanical and electrical properties will yield great advances in high-tech applications. These findings provide guidance for the future production of high performance graphene fibers. © 2013 The Royal Society of Chemistry.

Jiang H.,Sichuan University | Chen L.,Sichuan University | Chai S.,Guangdong Shengyi Technology Ltd Corporation | Yao X.,Sichuan University | And 2 more authors.
Composites Science and Technology | Year: 2014

Dispersion of graphene nanosheets (GNs) in a polymer matrix as mono layers was an important step towards fabricating high performance polymer/GNs nanocomposites. However, the insoluble and infusible properties of poly (tetrafluoroethylene) (PTFE) made the incorporation of nanofillers in PTFE matrix difficult. In this paper, a novel method based on poly (tetrafluoroethylene) (PTFE) latex that assured the fine dispersion of GNs in PTFE matrix was developed. PTFE latex was first modified by polyethylenimine (PEI) to create the positive charges on the surface of the PTFE particles, and then assembled with negatively charged graphene oxide sheets directly in water through electrostatic interaction, followed with chemical reduction, cold briquetting and hot sintering. Nanocomposites with controllable content and uniformly distributed GNs in PTFE matrix were prepared. The electrostatic coupling interactions improved the dispersion of GNs and facilitated the formation of filler networks in the PTFE matrix. Both the mechanical and wear performance of PTFE/GNs nanocomposites were greatly improved. PTFE/GNs nanocomposites also exhibited excellent electrical properties with a percolation threshold as low as 0.5. wt% and an electrical conductivity of 1.4. S/m at only 2. wt% graphene loadings. The new method agrees well with the latex technical process in PTFE bulk industrial manufacture and paves the way for an environmentally benign process for the bulk production of high quality polymer-graphene nanocomposites. © 2014 Elsevier Ltd.

Wu K.,Sichuan University | Wu L.,Sichuan University | Yang W.,Sichuan University | Chai S.,Guangdong Shengyi Technology Ltd Corporation | And 2 more authors.
RSC Advances | Year: 2016

It has been demonstrated that introducing another non-conductive particle into conductive filler filled composites could result in a better conductivity due to a volume exclusion effect. It was also reported that combining electrically conductive fillers with different geometric shapes and aspect ratio together could enhance the electrical conductivity due to the synergistic effect. To further explore these two effects on the electrical property enhancement, we firstly encapsulated neat silica (SiO2) with graphene oxide (GO) through electrostatic self-assembly to render SiO2 with surface conductivity. Then neat SiO2 or SiO2@GO together with multi-walled carbon nanotubes (MWCNT) were mixed with polystyrene (PS) to prepare conductive composites. In this way, the volume exclusion effect in the PS/MWCNT/SiO2 system and combined effect of volume exclusion and synergy in the PS/MWCNT/SiO2@rGO system could be investigated and compared. An obvious increased conductivity was observed only in the transition composition region for the PS/MWCNT/SiO2 system compared with the PS/MWCNT system. However, a largely enhanced conductivity was achieved through the composition region for the PS/MWCNT/SiO2@rGO system compared with the PS/MWCNT/SiO2 system and PS/MWCNT, accompanied by great enhancement of the electromagnetic interference (EMI) shielding effectiveness. Given the SEM characterization and rheological properties, we attributed this obvious enhanced electrical property to both a volume exclusion effect and a synergistic effect. © 2016 The Royal Society of Chemistry.

Deng S.,Sichuan University | Wang J.,Sichuan University | Zong G.,Sichuan University | Chen F.,Sichuan University | And 2 more authors.
RSC Advances | Year: 2016

The thermal conductivity of expanded graphite (EG)/polymer composites is investigated in terms of polymer chain structures. The EG/polyphenylene sulfide (PPS) composite with a backbone of benzene rings shows the continuous highest thermal conductivity and the fastest rate of enhanced ratio at the same content. Then it is followed by EG/syndiotactic polystyrene (sPS) composites with side groups of regularly arranged benzene rings. The last are the EG/amorphous polystyrene (aPS) composites with side groups of randomly arranged benzene rings. Our results show that the chain structures of polymer matrices have a great influence on the interaction and crystallization of EG/polymer composites, which leads to the different thermal behavior. More precisely, the strong π-π interaction between EG and polymer, the nucleation of crystal at the interface of EG/polymer and the relatively rich EG content in the amorphous phase are benefits to the enhancement of thermal conductivity. These factors are proved to be extremely important for the design of high thermally conductive composites in the fields of science and engineering. © The Royal Society of Chemistry 2016.

Zhang Y.,University of Sichuan | Chen L.,University of Sichuan | Chen L.,Guangdong Shengyi Technology Ltd Corporation | Zhao J.-J.,University of Sichuan | And 6 more authors.
Polymer Chemistry | Year: 2014

In this study, a novel phosphorus-containing ionic monomer, named sodium salt of 10H-phenoxaphosphine-2,8-dicarboxylic acid,10-hydroxy-,2,8- dihydroxyethyl ester,10-oxide (DHPPO-Na), was synthesized, characterized, and then copolymerized to prepare poly(ethylene terephthalate)-based ionomers. The chemical structure of the resulting ionomers was confirmed by 1H, 13C, and 31P NMR spectroscopy. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) were used to investigate the thermal properties of the ionomers. Compared with that of neat PET, the initial decomposition temperature of PETIs decreased in a nitrogen atmosphere while it increased in air. The crystallinity of PETIs was enhanced firstly and then destroyed with the ionic group increase. The limiting oxygen index (LOI) test and cone calorimeter were used to characterize the flame-retardant properties of the ionomers. The results showed that the introduction of DHPPO-Na could endow an expected flame-retardant performance, meanwhile it considerably restricted the melt-dripping behavior and suppressed the smoke release. The rheology test confirmed that the ionic groups increased the melt viscosity via ionic aggregation during heating, which was a benefit for the flame-retardant property of the copolyester. This journal is © The Royal Society of Chemistry.

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