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Diercks C.S.,King Abdulaziz City for Science and Technology | Yaghi O.M.,University of California at Berkeley | Yaghi O.M.,Lawrence Berkeley National Laboratory | Yaghi O.M.,Kavli Energy NanoSciences Institute | Yaghi O.M.,Berkeley Global Science Institute
Science | Year: 2017

Just over a century ago, Lewis published his seminal work on what became known as the covalent bond, which has since occupied a central role in the theory of making organic molecules. With the advent of covalent organic frameworks (COFs), the chemistry of the covalent bond was extended to two- and three-dimensional frameworks. Here, organic molecules are linked by covalent bonds to yield crystalline, porous COFs from light elements (boron, carbon, nitrogen, oxygen, and silicon) that are characterized by high architectural and chemical robustness. This discovery paved the way for carrying out chemistry on frameworks without losing their porosity or crystallinity, and in turn achieving designed properties in materials. The recent union of the covalent and the mechanical bond in the COF provides the opportunity for making woven structures that incorporate flexibility and dynamics into frameworks.

News Article | April 17, 2017

Severe water shortages already affect many regions around the world, and are expected to get much worse as the population grows and the climate heats up. But a new technology developed by scientists at MIT and the University of California at Berkeley could provide a novel way of obtaining clean, fresh water almost anywhere on Earth, by drawing water directly from moisture in the air even in the driest of locations. Technologies exist for extracting water from very moist air, such as “fog harvesting” systems that have been deployed in a number of coastal locations. And there are very expensive ways of removing moisture from drier air. But the new method is the first that has potential for widespread use in virtually any location, regardless of humidity levels, the researchers say. They have developed a completely passive system that is based on a foam-like material that draws moisture into its pores and is powered entirely by solar heat. The findings are reported in the journal Science by a team including MIT associate professor of mechanical engineering Evelyn Wang, MIT postdoc Sameer Rao, graduate student Hyunho Kim, research scientists Sungwoo Yang and Shankar Narayanan (currently at Rensselaer Polytechnic Institute), and alumnus Ari Umans SM ’15. The Berkeley co-authors include graduate student Eugene Kapustin, project scientist Hiroyasu Furukawa, and professor of chemistry Omar Yaghi. Fog harvesting, which is being used in many countries including Chile and Morocco, requires very moist air, with a relative humidity of 100 percent, explains Wang, who is the Gail E. Kendall Professor at MIT. But such water-saturated air is only common in very limited regions. Another method of obtaining water in dry regions is called dew harvesting, in which a surface is chilled so that water will condense on it, as it does on the outside of a cold glass on a hot summer day, but it “is extremely energy intensive” to keep the surface cool, she says, and even then the method may not work at a relative humidity lower than about 50 percent. The new system does not have these limitations. For drier air than that, which is commonplace in arid regions around the world, no previous technology provided a practical way of getting water. “There are desert areas around the world with around 20 percent humidity,” where potable water is a pressing need, “but there really hasn’t been a technology available that could fill” that need, Wang says. The new system, by contrast, is “completely passive — all you need is sunlight,” with no need for an outside energy supply and no moving parts. In fact, the system doesn’t even require sunlight — all it needs is some source of heat, which could even be a wood fire. “There are a lot of places where there is biomass available to burn and where water is scarce,” Rao says. The key to the new system lies in the porous material itself, which is part of a family of compounds known as metal-organic frameworks (MOFs). Invented by Yaghi two decades ago, these compounds form a kind of sponge-like configuration with large internal surface areas. By tuning the exact chemical composition of the MOF these surfaces can be made hydrophilic, or water-attracting. The team found that when this material is placed between a top surface that is painted black to absorb solar heat, and a lower surface that is kept at the same temperature as the outside air, water is released from the pores as vapor and is naturally driven by the temperature and concentration difference to drip down as liquid and collect on the cooler lower surface. Tests showed that one kilogram (just over two pounds) of the material could collect about three quarts of fresh water per day, about enough to supply drinking water for one person, from very dry air with a humidity of just 20 percent. Such systems would only require attention a few times a day to collect the water, open the device to let in fresh air, and begin the next cycle. What’s more, MOFs can be made by combining many different metals with any of hundreds of organic compounds, yielding a virtually limitless variety of different compositions, which can be “tuned” to meet a particular need. So far more than 20,000 varieties of MOFs have been made. “By carefully designing this material, we can have surface properties that can absorb water very efficiently at 50 percent humidity, but with a different design, it can work at 30 percent,” says Kim. “By selecting the right materials, we can make it suitable for different conditions. Eventually we can harvest water from the entire spectrum” of water concentrations, he says. Yaghi, who is the founding director of the Berkeley Global Science Institute, says “One vision for the future is to have water off-grid, where you have a device at home running on ambient solar for delivering water that satisfies the needs of a household. … To me, that will be made possible because of this experiment. I call it personalized water.” While these initial experiments have proved that the concept can work, the team says there is more work to be done in refining the design and searching for even more effective varieties of MOFs. The present version can collect water up to about 25 percent of its own weight, but with further tuning they think that proportion could be at least doubled. “Wow, that is an amazing technology,” says Yang Yang, a professor of engineering at the University of California at Los Angeles, who was not involved in this work. “It will have a tremendous scientific and technical impact on renewable and sustainable resources, such as water and solar energy.” The work was supported in part by ARPA-E, a program of the U.S. Department of Energy.

Huh D.N.,University of California at Irvine | Czer E.T.,University of Kansas | Cordova K.E.,Berkeley Global Science Institute | Chow W.I.,University of San Diego | And 3 more authors.
Inorganica Chimica Acta | Year: 2016

The complex Ru((R,R)-DACH-Naph)Cl2 ((R,R)-2), a neutral Ru(II) complex of the Trost diamido-bis(phosphine) ligand ((R,R)-DACH-Naph (H21)) was synthesized in 86% yield via the direct stoichiometric reaction of H21 and RuCl2(DMSO)4 in refluxing toluene. Complex (R,R)-2 was further reacted with excess [NO][BF4] producing Ru((HON)2-DICH-Naph)Cl2 (4) in 48% yield; a Ru(II) complex where the Trost ligand has been oxidized to a diimine and nitrosylated, on the backbone cyclohexyl ring, to a dioxime. The structures of (R,R)-2 and 4 were revealed in the solid state by single-crystal X-ray analysis and in the solution state via 1H NMR spectroscopy.

Lee S.,University of California at Berkeley | Lee S.,Lawrence Berkeley National Laboratory | Lee S.,Kavli Energy NanoSciences Institute | Lee S.,Berkeley Global Science Institute | And 9 more authors.
Science | Year: 2016

A chiral metal-organic framework, MOF-520, was used to coordinatively bind and align molecules of varying size, complexity, and functionality. The reduced motional degrees of freedom obtained with this coordinative alignment method allowed the structures of molecules to be determined by single-crystal x-ray diffraction techniques. The chirality of the MOF backbone also served as a reference in the structure solution for an unambiguous assignment of the absolute configuration of bound molecules. Sixteen molecules representing four common functional groups (primary alcohol, phenol, vicinal diol, and carboxylic acid), ranging in complexity from methanol to plant hormones (gibberellins, containing eight stereocenters), were crystallized and had their precise structure determined. We distinguished single and double bonds in gibberellins, and we enantioselectively crystallized racemic jasmonic acid, whose absolute configuration had only been inferred from derivatives.

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