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Danov S.M.,Dzerzhinsk Polytechnic Institute | Sulimov A.V.,Dzerzhinsk Polytechnic Institute | Ovcharova A.V.,Dzerzhinsk Polytechnic Institute
Theoretical Foundations of Chemical Engineering | Year: 2012

The parameters of the NRTL and UNIQUAC models have been estimated for the system formed by epichlorohydrin synthesis products. Mathematical modeling of the vapor-liquid equilibrium in two- and three-component systems at atmospheric pressure has been carried out. © Pleiades Publishing, Ltd., 2012.


Danov S.M.,Dzerzhinsk Polytechnic Institute | Sulimov A.V.,Dzerzhinsk Polytechnic Institute | Kolesnikov V.A.,Dzerzhinsk Polytechnic Institute | Ovcharova A.V.,Dzerzhinsk Polytechnic Institute
Kinetics and Catalysis | Year: 2011

The kinetics of allyl chloride oxidation to epichlorohydrin in the presence of titanium-containing zeolite was studied. The influence of the concentrations of the initial substances, reaction products, and tem-perature on the rate of the process was considered. The mathematical model of the process was constructed on the basis of the experimental data obtained. The rate constants, adsorption equilibrium constants, and activation energies of the reactions were calculated. © Pleiades Publishing, Ltd., 2011.

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