Di Mendeleyev Institute For Metrology

Saint Petersburg, Russia

Di Mendeleyev Institute For Metrology

Saint Petersburg, Russia
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Taymanov R.,Di Mendeleyev Institute For Metrology | Sapozhnikova K.,Di Mendeleyev Institute For Metrology
Journal of Physics: Conference Series | Year: 2016

The necessity for developing metrology due to extension of its application sphere is noted. The efficiency of the metrological approach to measurement of multidimensional quantities in the field of humanities is shown using the development of cultural capital interpreted by L. Harrison. The cultural capital is defined as a measure of the society structure complexity and adaptive capacity. © Published under licence by IOP Publishing Ltd.

Antonov N.V.,Saint Petersburg State University | Gulitskiy N.M.,Di Mendeleyev Institute For Metrology
Lecture Notes in Computer Science (including subseries Lecture Notes in Artificial Intelligence and Lecture Notes in Bioinformatics) | Year: 2012

The problem of anomalous scaling in magnetohydrodynamics turbulence is considered within the framework of the kinematic approximation, in the presence of a large-scale background magnetic field. Field theoretic renormalization group methods are applied to the Kazantsev-Kraichnan model of a passive vector advected by the Gaussian velocity field with zero mean and correlation function α δ(t-t′)/k d+ε. Inertial-range anomalous scaling for the tensor pair correlators is established as a consequence of the existence in the corresponding operator product expansions of certain "dangerous" composite operators, whose negative critical dimensions determine the anomalous exponents. The main technical result is the calculation of the anomalous exponents in the order ε 2 of the ε expansion (two-loop approximation). © 2012 Springer-Verlag.

Taymanov R.,Di Mendeleyev Institute For Metrology | Sapozhnikova K.,Di Mendeleyev Institute For Metrology
EPJ Web of Conferences | Year: 2014

In the paper it is shown that at present the problem of measurements of emotions as multidimensional (multiparametric) quantities is of interest. A measurement model developed by the authors is presented. It enables signals-stimuli generating emotions in sound combinations and their series to be selected and quantitatively estimated. The measurement model provides an adjusted delay (short-time memory) and joint non-linear conversion of audible and delayed acoustical signals, selection of infrasound signals-stimuli as well as identification of emotional images including the ensembles of signals-stimuli and their series. It is demonstrated how the "mechanism" of emotional perception of sound impacts was developed in the process of evolution. Possibilities to decode the emotional content of biolinguistic signals of animals are considered. Future trends of investigations are indicated. © Owned by the authors, published by EDP Sciences, 2014.

Taymanov R.,Di Mendeleyev Institute For Metrology | Sapozhnikova K.,Di Mendeleyev Institute For Metrology
Measurement: Journal of the International Measurement Confederation | Year: 2010

There are growing indications of a crisis in conventional methods of metrological assurance for measuring instruments with built-in self-checking. This paper offers an analysis, looking in the first instance at sensors. An analogy between biological and technical evolution is discussed. It is argued that the future will see intelligent sensors and measuring systems being mass produced with inbuilt metrological self-checking, as well as the transition to a new stage in the evolution of metrological assurance of sensors. © 2010 Elsevier Ltd. All rights reserved.

Kadis R.,Di Mendeleyev Institute For Metrology | Leito I.,University of Tartu
Analytica Chimica Acta | Year: 2010

The residual liquid junction potential (RLJP) needs to be accounted for in pH uncertainty estimation. Attempts to do this and the currently available methods for evaluating the RLJP are critically discussed and their weak sides are pointed out. In this work an empirical approach to the problem is proposed. It is based on the use of the RLJP bias estimated on a variety of measurement conditions for a specific class of analytical objects essentially differing in ionic strength from the pH calibration buffers. The data from five independent studies, including interlaboratory comparisons, on pH measurement in low ionic strength waters were used to find the overall bias observed in the 10-4moldm-3 strong acid solution. The procedure includes quantifying the uncertainty of bias values from separate studies by combination of the relevant uncertainty components and testing the consistency of the data. The weighted mean bias in pH was found to be 0.043±0.007 (k=2). With this estimate, the pH measurement uncertainties calculated according to the previously suggested procedure (I. Leito, L. Strauss, E. Koort, V. Pihl, Accredit. Qual. Assur. 7 (2002) 242-249.) can be enlarged to take the uncorrected bias into account. The resulting uncertainties on the level of 0.10-0.14 (k=2) are obtained in this way for pH measurement in water and poorly buffered aqueous solutions in the range of pH 7.5-3.5. © 2010 Elsevier B.V.

Pokhodun A.I.,Di Mendeleyev Institute For Metrology
AIP Conference Proceedings | Year: 2013

The paper deals with results of an analysis carried out at the VNIIM with the purpose to ascertain the current status of thermometry as well as to make an attempt to determine a line of development of this field of measurements in future. The analysis was based on a survey of 150 industrial enterprises and scientific organizations. The results of the survey showed that during two last decades the accuracy of measuring instruments used in science and industry was increased almost tenfold. However, advances in the improvement of temperature measuring instruments were achieved not owing to new principles of designing thermometers, but due to rapid development of electronics, which allowed to solve the problem of accurate measurements of resistance and electromotive force and automatize measurement information processing. In most cases the contemporary measuring instruments perfectly meet the requirements to the measurement accuracy claimed by the enterprises surveyed and are provided with a necessary metrological assurance. Although there is a general understanding of the necessity to use the thermodynamic scale rather than the conditional one, we have no objective evidence with regard to how close we have to bring the international scale used in our everyday practice to the thermodynamic scale and what will be a benefit for development of science and industry. Increasing the accuracy of national standards does not affect, as a rule, the accuracy of temperature measurements in industry and scientific research since the main contribution to a total measurement error is made by components caused by an improper measurement procedure. © 2013 AIP Publishing LLC.

Sapozhnikova K.,Di Mendeleyev Institute For Metrology | Chunovkina A.,Di Mendeleyev Institute For Metrology | Taymanov R.,Di Mendeleyev Institute For Metrology
Measurement: Journal of the International Measurement Confederation | Year: 2014

The paper comments on the definitions of such terms as "measurement, " "nominal property," "metrological traceability," and others given in the 3-rd edition of International Vocabulary of Metrology (VIM). Proposals are offered for amendments to the terminology of the next edition of the VIM, taking into account new fields where measurements are applied. © 2013 Elsevier Ltd. All rights reserved.

Kustikov Y.A.,Di Mendeleyev Institute For Metrology | Popov B.I.,Di Mendeleyev Institute For Metrology
Mapan - Journal of Metrology Society of India | Year: 2013

Aerodisperse system (ambient aerosol) is a dynamic system, thus its physical and chemical properties change continuously in the atmosphere. In addition to the changing characteristic of atmospheric aerosols, their accurate and precise measurements are a challenging task because these measurements depend on several parameters for which the traceable standards/calibration are essentially required. In Russia, the traceability for these measurements is provided in accordance with the recommendations of the Russian national regulatory standard "State hierarchy scheme for the instruments deployed for the measurements of the disperse parameters of aerosols, suspensions and powdered materials." The State primary standard for the units of disperse parameters of aerosols, suspensions and powdered materials (GET-163) and the State primary special standard for the unit of mass concentration of particles in aerodispersed media (GET-164) are placed at the top of the hierarchy scheme. This paper describes the State primary special standard GET-164 and the specificity of ensuring the traceability in disseminating the unit realized by this primary special standard to working measurement instruments. Methods used to generate aerodispersed media with desired properties are validated and the problem for achieving the highest accuracy in the measurements related to the primary special standard GET-164 is discussed. The SI unit of mass concentration of particulate matter is disseminated from the State primary special standard GET-164 to the working instruments through a set of working standards. The methods, which are used to generate aerodispersed media in disseminating the unit of mass concentration, provided for carrying out investigations and calibration of measurement instruments over a wide range of the mass concentration of suspended particles of different disperse composition. The main ways of improving the standard facilities in the field of measurements of the mass concentration of suspended particles are (i) related to the improvement of the method used to measure concentrations by means of a beta-ray analyzer-comparator (included in the composition of the State primary special standard GET-164) by reducing the uncertainty of the approximation of the conversion characteristics and (ii) due to implementation of methods providing for accurately controlled dilution of aerosols to extend the ranges in which the mass concentration values of suspended particles are reproduced. In order to develop a procedure for international comparisons of such standards, the corresponding investigations of the State primary special standard GET-164 were carried out. © 2013 Metrology Society of India.

Milman B.L.,Di Mendeleyev Institute For Metrology | Zhurkovich I.K.,All Russia Institute of Plant Protection
Rapid Communications in Mass Spectrometry | Year: 2011

To gain perspective on building full transferable libraries of MSn spectra from their diverse/numerous collections, a new library was built from 1723 MS>1 spectra (mainlyMS2 spectra) of 490 pesticides and related compounds. Spectra acquired on different types of tandem instruments in various experimental conditions were extracted from 168 literature articles and Internet sites. Testing of the library was based on searches where 'unknown' and reference spectra originated from different sources (mainly from different laboratories) were cross-compared. The NIST 05 MS2 library was added to the reference spectra. The library searches were performed with all the test spectra or were divided into different subsamples containing (a) various numbers of replicate spectra of test compounds or (b) spectra acquired from different instrument types. Thus, the dependence of true/false search (identification) result rates on different factors was explored. The percentage of 1st rank correct identifications (true positives) for the only 'unknown' mass spectrum and two and more reference spectra and matching precursor ion m/z values was 89%. For qualified matches, above the cut-off match factor, that rate decreased to 80%. The corresponding rates based on the best match for two and more 'unknown' and reference spectral replicates were 89-94%. For quadrupole instruments, the rates were even higher: 91-95% (one 'unknown' spectrum) and 90-100% (two and more such spectra). This study shows that MS2 spectral libraries generated from the numerous literature/Internet sources are not less efficient for the goal of identification of unknown compounds including pesticides than very common EI-MS1 libraries and are almost as efficient as the most productive from current MS2 spectral databases. Such libraries may be used as individual reference databases or supplements to large experimental spectral collections covering many groups of abundant compounds and different types of tandem mass spectrometers. Copyright © 2011 John Wiley & Sons, Ltd.

Gubler G.B.,Di Mendeleyev Institute For Metrology
CPEM Digest (Conference on Precision Electromagnetic Measurements) | Year: 2010

The paper considers a way for extending the bandwidth of integration-type digital voltmeters (DVM) that measure RMS values and harmonic ratios of signals. The method is applicable to measurements within frequency range commonly used for determining power quality parameters. In the course of experimental study the DVM had demonstrated non-uniformity of its amplitude-frequency response less than ±20 μV/V within the 50 to 3300 Hz band. © 2010 IEEE.

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