Daelim Industrial Co. | Date: 2016-01-13
Disclosed is a method of olefin polymerization that enables production of polyolefin with high productivity while suppressing sheeting or caking in the reactor. The method of olefin polymerization includes: feeding a circulating gas including at least one alpha-olefin and an inert gas into a reactor; polymerizing the alpha-olefin into a polyolefin in a reaction region in the reactor; and discharging the polyolefin from the reactor, which reactor consists of a cylindrical base section a positioned in the lower part thereof and a conical top section b positioned on the top of the cylindrical base section and having an open top. The conical top section b has an angle of inclination in the range of 4 to 7 with respect to a perpendicular line. The inside of the reactor is divided into a reaction region A that is a fluidized bed region having an olefin polymerization occurring therein, and a free region B positioned on the top of the reaction region A and having solid polyolefin particles separated from the gas phase. The fluidized bed is at least as high as the cylindrical base section a and 80 percent or less the height of the conical top section b.
Daelim Industrial Co. | Date: 2016-11-16
Disclosed are an apparatus and a method for polymerization that can economically copolymerize ethylene and alpha-olefin by reusing reacting raw materials and solvents. The apparatus for polymerization of ethylene and alpha-olefin comprises: a polymerization reactor in which ethylene and alpha-olefin are supplied as reaction raw materials along with a solvent, and the reaction raw materials are copolymerized in a solution state, to thereby produce a polymerization product comprising an ethylene and alpha-olefin copolymer dissolved in the solvent; a unit for separating unreacted ethylene, alpha-olefin, low molecular weight oligomer and a polymer, including a flash tower for distilling and separating the unreacted ethylene and alpha-olefin contained in the polymerization product, and a stripper unit for distilling and separating the solvent and the low molecular weight oligomer having a lower molecular weight than the molecular weight of the ethylene and alpha-olefin copolymer contained in the polymerization product; and a solvent recovery unit for separating the low molecular weight oligomer from the separated low molecular weight oligomer and solvent and recovering the solvent.
Daelim Industrial Co. | Date: 2016-04-13
Disclosed are an apparatus and method for preparing polybutene having various molecular weights by using complex catalysts of different molar ratios. The apparatus for preparing polybutene having various molecular weights, comprises: a complex catalyst preparing device for preparing a high-activity complex catalyst and a low-activity complex catalyst to form highly reactive polybutene through polymerization; a high-molar ratio complex catalyst system for controlling the storage and supply of the high-activity complex catalyst; a low-molar ratio complex catalyst system for controlling the storage and supply of the low-activity complex catalyst; and a reactor to which reaction raw materials including the high-activity complex catalyst, the low-activity complex catalyst, and isobutene are supplied to be polymerized into highly reactive polybutene.
Daelim Industrial Co. | Date: 2016-03-23
There are disclosed an apparatus and a method for selectively preparing a high reactivity polybutene, a midrange reactivity polybutene and a non-reactive polybutene in a single plant. The apparatus for selectively preparing a reactive polybutene and a non-reactive polybutene, comprises: a reactive polybutene polymerization catalyst feeder for polymerization of the reactive polybutene; a non-reactive polybutene polymerization catalyst feeder for polymerization of the non-reactive polybutene; and a reactor for polymerizing a reactant including isobutene into polybutene, wherein the reactive polybutene polymerization catalyst feeder provides a catalyst to yield the reactive polybutene; and the non-reactive polybutene polymerization catalyst feeder provides a catalyst to yield the non-reactive polybutene.
Daelim Industrial Co. | Date: 2015-09-23
A liquid random copolymer of ethylene and alpha-olefin prepared by using specific metallocene catalyst and ionic compound and a method for preparing the same are disclosed. The liquid random copolymer has high viscosity index and shear stability so that it is useful as synthetic lubricants. The liquid random copolymer of ethylene and alpha-olefin (1) comprises 60 to 40 mol% of ethylene units and 40 to 60 mol% of alpha-olefin unit having 3 to 20 carbon atoms, (2) has number average molecular weight (Mn) of 500 to 10,000 and a molecular weight distribution (Mw/Mn, Mw is the weight average molecular weight) of 3 or less measured by Gel Permeation Chromatography (GPC) (3) has Kinematic Viscosity at 100 C of 30 to 5,000, (4) has pour point of 30 to -45 C, and (5) has Bromine Number of 0.1 or less.
Daelim Industrial Co. | Date: 2016-06-08
Disclosed are a device and a method for continuously polymerizing polybutene by removing halogen acid, which is included in a reaction raw material, by adsorbing the halogen acid using an adsorbent and then re-supplying the reaction raw material into a reactor. The device for re-circulating the raw material when manufacturing polybutene comprises a reactor, into which a catalyst and a reaction raw material (diluted with an inactive organic solvent) are supplied and polymerized to produce a reaction product; a neutralizing/washing tank for removing the catalyst from the reaction product and neutralizing the reaction product; a separation tank for separating the reaction product into organic compounds and water; a C4 distillation column for distilling an unreacted raw material and the inactive organic solvent from the organic compounds; and an impurity adsorption column for removing halogen acid from the distilled unreacted raw material and the inactive organic solvent using an adsorbent.
Daelim Industrial Co. | Date: 2016-07-06
Disclosed are an apparatus and a method for removing halogens generated during the preparation of polybutene, which are capable of improving the utilization of polybutene and light polymers by removing halogen components contained in the polybutene and the light polymers. The method for removing halogens generated during the preparation of polybutene comprises the steps of: preparing a reaction product by supplying a catalyst and a reaction raw material to a reactor and polymerizing; removing a catalyst component from the reaction product and neutralizing; separating the reaction product into an organic compound and impurities comprising the catalyst component; heating the organic compound to distill an unreacted material; and removing a halogen component in a remaining polymerization mixture after the distillation using a halogen removing catalyst, or removing a halogen component in polybutene and light polymers obtained from the polymerization mixture using the halogen removing catalyst.
Daelim Industrial Co. | Date: 2015-10-07
A metallocene catalyst composition for preparing multimodal polyolefin resin which has superior moldability, mechanical strength, appearance and so on, and a polymerization method using the same are disclosed. The catalyst composition comprises (i) at least one first metallocene compound represented by Formula 1 in the description part:(ii) at least one second metallocene compound represented by Formula 2 in the description of the Specification: and a co-catalyst.
Daelim Industrial Co. | Date: 2015-09-16
A method for removing the fluorine component from waste water which is produced during the manufacturing process of highly reactive polybutene and contains high concentration of fluorine component is disclosed. The method comprises a step of adding to the waste water a treating agent selected from a group of Al compound, Ca compound and mixture thereof at temperature of 50 to 300C for reaction, whereby boron trifluoride neutralized salt is decomposed to form Al salt or Ca salt of fluorine component so that the fluorine component is removed in the form of the Al salt or the Ca salt of fluorine component.
Daelim Industrial Co. | Date: 2015-02-04
Multimodal polyolefin resin having excellent characteristics such as moldability, mechanical strength, external appearance and a polyolefin resin molded product are disclosed. The polyolefin resin satisfies all requirements of following (1) to (5), (1) density (d): 0.934 to 0.963 g/cm3, (2) melt flow index(MIE, 190C, 2.16 kg load condition): 0.01 to 1.0 g/10 minutes, (3) ratio of weight-average molecular weight (Mw) and number-average molecular weight (Mn) measured by Gel Permeation Chromatography (GPC) (Mw/Mn, Molecular weight distribution (MWD)): 12 to 60, (4) at least two peaks appear when the molecular weight of the polyolefin resin is measured with GPC, and (5) amount of polyolefin having Mw of 10,000 or less exceeds 15 weight% and amount of polyolefin having Mw of 1,000,000 or more exceeds 1.5 weight%, when the molecular weight of the polyolefin resin is measured with GPC.