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Ferruti P.,Consortium for Science and Technology of Materials
Journal of Polymer Science, Part A: Polymer Chemistry | Year: 2013

Poly(amidoamine)s (PAAs) are a family of synthetic polymers obtained by stepwise polyaddition of prim- or sec-amines to bisacrylamides. Nearly all conceivable bisacrylamides and prim- or sec-amines can be employed as monomers endowing PAAs of a structural versatility nearly unique among stepwise polyaddition polymers. PAAs are degradable in aqueous media, including physiological fluids. Many of them are remarkably biocompatible notwithstanding their cationic character. PAAs are per se highly functional polymers and, in addition, can be further functionalized giving rise to an endless variety of polymeric structures meeting the requisites for applications in such apparently disparate fields as inorganic water pollutants scavengers, sensors, drug and protein intracellular carriers, transfection promoters, peptidomimetic antiviral and antimalarial agents. In this review, the unique chemistry of PAAs is discussed and a vast library of PAA structures and PAA applications from the beginning to the present days reported. © 2013 Wiley Periodicals, Inc. Source


Lebeau B.,CNRS Mulhouse Institute of Materials Science | Innocenzi P.,Consortium for Science and Technology of Materials
Chemical Society Reviews | Year: 2011

The interest in organic-inorganic hybrids as materials for optics and photonics started more than 25 years ago and since then has known a continuous and strong growth. The high versatility of sol-gel processing offers a wide range of possibilities to design tailor-made materials in terms of structure, texture, functionality, properties and shape modelling. From the first hybrid material with optical functional properties that has been obtained by incorporation of an organic dye in a silica matrix, the research in the field has quickly evolved towards more sophisticated systems, such as multifunctional and/or multicomponent materials, nanoscale and self-assembled hybrids and devices for integrated optics. In the present critical review, we have focused our attention on three main research areas: passive and active optical hybrid sol-gel materials, and integrated optics. This is far from exhaustive but enough to give an overview of the huge potential of these materials in photonics and optics (254 references). © 2011 The Royal Society of Chemistry. Source


Gross S.,CNR Institute of Molecular Science and Technologies | Gross S.,Consortium for Science and Technology of Materials
Journal of Materials Chemistry | Year: 2011

The focus of this Highlight is on the structural and functional properties which organically modified transition oxoclusters can provide, once embedded into a polymer matrix, to the resulting hybrid materials. Some selected case studies are discussed to highlight the role of these polynuclear inorganic building blocks in determining appealing material properties. © 2011 The Royal Society of Chemistry. Source


Grant
Agency: Cordis | Branch: H2020 | Program: IA | Phase: NMP-21-2014 | Award Amount: 6.97M | Year: 2015

The project NANO-CATHEDRAL aims at developing, with a nano-metric scale approach, new materials, technologies and procedures for the conservation of deteriorated stones in monumental buildings and cathedrals and high value contemporary architecture, with a particular emphasis on the preservation of the originality and specificity of materials. The objective is providing key tools for restoration and conservation: On representative lithotypes On European representative climatic areas With a time-scale/environmental approach With technology validated in relevant environment (industrial plant and monuments) Exploiting results also on modern stone made buildings A general protocol will be defined for the identification of the petrographic and mineralogical features of the stone materials, the identification of the degradation patterns, the evaluation of the causes and mechanisms of alteration and degradation, including the correlations between the relevant state of decay and the actual microclimatic and air pollution conditions. Moreover, innovative nano-materials will be developed suitable for: Surface consolidation: in this case water-based formulations based on nano-inorganic or nano-hybrid dispersions such as nano-silica, nano-titania, nano-hydroxyapatite, nano-calcite and nano-magnesia as well as their synergic combinations with organic and inorganic compounds will be considered. Surface protection: in this case, innovative composites will be developed consisting of polymers and nano-fillers. The use of hydrophobins, nano-assembled hydrofobic proteins extracted from fungi, and photocatalytic nano-particles (for favoring the decomposition of volatile organic molecules carried by polluted atmosphere and to prevent biofilm growth) will be considered. The project will contribute to the development of transnational cultural tourism and to the development of common European shared values and heritage, thus stimulating a greater sense of European identity.


Grant
Agency: Cordis | Branch: H2020 | Program: RIA | Phase: LCE-21-2015 | Award Amount: 3.74M | Year: 2016

The transition to a low carbon economy needs to achieve multiple aims: competitiveness, protection of the environment, creation of quality jobs, and social welfare. Thus policy-makers and other key stakeholders require tools that need to focus beyond the energy sector by including these other domains of economy, society and the environment. Currently, most available tools lack integration of these important areas despite being tightly connected to the energy sector. Moreover, current energy modelling tools often lack documentation, transparency and have been developed for a specialized insider audience, which makes validation and comparison of results as well as independent review impossible. Our project aims to solve the current needs of integration and transparency by developing a leading-edge policy modelling tool based on WoLiM, TIMES and LEAP models and incorporating Input-Output Analysis, that allows for accounting of environmental, social and economic impacts. The modular design of the tool will take into account the necessary flexibility to deal with different levels and interests of stakeholders at great sectorial and spatial detail. Finally, transparency will be achieved through an open access freeware distribution of the model based on the open access programming language (Python), providing a detailed user manual, addressed to a wider non-specialist audience, and including free internet courses and learning materials.

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