Entity

Time filter

Source Type


Guo Z.,Nanjing University of Information Science and Technology | Guo Z.,Collaorative Innovation Center Atmospheric Environment and Equipment Technology | Jiang W.,Nanjing University of Information Science and Technology | Jiang W.,Collaorative Innovation Center Atmospheric Environment and Equipment Technology | And 9 more authors.
Atmospheric Research | Year: 2016

Stable isotopic compositions (δ13C) of elemental carbon (EC) in PM1.1 in north suburb of Nanjing region were determined in order to quantitatively evaluate the carbon sources of atmospheric fine particles during different seasons. Besides, δ13C values from potential sources such as coal combustion, vehicle exhaust, biomass burning, and dust were synchronously measured. The results showed that the average δ13C values of EC in PM1.1 in winter and summer were -23.89±1.6‰ and -24.76±0.9‰, respectively. Comparing with δ13C values from potential sources, we concluded that the main sources of EC in PM1.1 were from the emission of coal combustion and vehicle exhaust. The higher δ13C values in winter than those in summer were chiefly attributed to the more coal consumption. Combining with the concentrations of SO42- and K+ in PM1.1, the high δ13C values of EC on 24 December and 27 December 2013 were ascribed to extra input of corn straw burning in addition to coal combustion and vehicle exhaust. © 2015 Elsevier B.V. Source


Guo Z.,Nanjing University of Information Science and Technology | Guo Z.,Collaorative Innovation Center Atmospheric Environment and Equipment Technology | Shi L.,Nanjing University of Information Science and Technology | Shi L.,Collaorative Innovation Center Atmospheric Environment and Equipment Technology | And 10 more authors.
Atmospheric Research | Year: 2016

Sulfur isotopic compositions (δ34S) of PM2.5 in Nanjing region were determined in order to evaluate sulfur sources of PM2.5 around the second session of the Youth Olympic Games (YOG). Meanwhile, δ34S values from different potential sources of PM2.5, such as coal combustion, vehicle exhaust, and straw burning, were synchronously measured for the first time. The results showed that PM2.5 concentrations and δ34S values were much lower during the YOG (2 August to 11 September 2014) compared to those before (6 July to 1 August 2014) and after (15 September to 20 September 2014) the YOG. δ34S values of PM2.5 were generally located in a small range of 3.5‰ to 4.6‰, suggesting a stable sulfur sources in Nanjing region around the YOG. Combining with δ34S values of potential sources and SO2, ion concentrations of PM2.5 and MODIS fire spot photos, we inferred that sulfur in PM2.5 was mainly from direct emission of coal combustion and vehicle exhaust as well as the secondary sulfate from SO2 oxidation in the atmosphere. Besides, biologic sulfur release might make a contribution to sulfur content in PM2.5. High [NO3 -]/[SO4 2-] ratio of PM2.5 indicated that vehicle exhaust emission was predominant over coal combustion during the YOG. In addition, we studied sulfur isotopic fractionation coefficients during SO2 oxidation to sulfate in PM2.5 and found the contribution ratio (51.3%) of SO2 homogeneous oxidation was slightly higher than that (48.7%) of SO2 heterogeneous oxidation around the YOG. © 2016 Elsevier B.V. Source

Discover hidden collaborations