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Liu H.-L.,CAS Shanghai Institute of Organic Chemistry | Peng Q.,CAS Shanghai Institute of Organic Chemistry | Wu Y.-D.,CAS Shanghai Institute of Organic Chemistry | Wu Y.-D.,Clear Technology | And 4 more authors.
Angewandte Chemie - International Edition | Year: 2010

(Figure Presented) The shining: Readily accessible BINOL amino alcohol (S)-I is a highly enantioselective fluorescent sensor for structurally diverse α-hydroxycarboxylic acids, and is the first highly enantioselective fluorescent sensor for the recognition of linear aliphatic α- hydroxycarboxylic acids and α-tertiary-hydroxycarboxylic acids. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

Peng C.,Tongji University | Chen B.,Tongji University | Qin Y.,Tongji University | Yang S.,Clear Technology | And 4 more authors.
ACS Nano | Year: 2012

In this paper, we report a facile ultrasonic method to synthesize well-dispersed CoO quantum dots (3-8 nm) on graphene nanosheets at room temperature by employing Co 4(CO) 12 as cobalt precursor. The prepared CoO/graphene composites displayed high performance as an anode material for lithium-ion battery, such as high reversible lithium storage capacity (1592 mAh g -1 after 50 cycles), high Coulombic efficiency (over 95%), excellent cycling stability, and high rate capability (1008 mAh g -1 with a total retention of 77.6% after 50 cycles at a current density of 1000 mA g -1, dramatically increased from the initial 50 mA g -1). The extraordinary performance arises from the structure advantages of the composites: the nanosized CoO quantum dots with high dispersity on conductive graphene substrates supply not only large quantity of accessible active sites for lithium-ion insertion but also good conductivity and short diffusion length for lithium ions, which are beneficial for high capacity and rate capability. Meanwhile, the isolated CoO quantum dots anchored tightly on the graphene nanosheets can effectively circumvent the volume expansion/contraction associated with lithium insertion/extraction during discharge/charge processes, which is good for high capacity as well as cycling stability. Moreover, regarding the anomalous behavior of capacity increase with cycles (activation effect) observed, we proposed a tentative hypothesis stressing the competition between the conductivity increase and the amorphorization of the composite electrodes during cycling in determining the trends of the capacity, in the hope to gain a fuller understanding of the inner working of the novel nanostructured electrode-based lithium-ion batteries. © 2012 American Chemical Society.

Protein phosphorylation is one type of posttranslational modification, which regulates a large number of cellular processes in plant cells. As an emerging powerful biotechnology that integrates all aspects of advantages from mass spectrometry, bioinformatics, and genomics, phosphoproteomics offers us an unprecedented high-throughput methodology with high sensitivity and dashing speed in identifying a large complement of phosphoproteins from plant cells within a relatively short period of time. Needless to say, phosphoproteomics has become an integral portion of life sciences, which penetrates various research disciplines of biology, agriculture, and forestry and irreversibly changes the way by which plant scientists study biological problems.Because phosphorylation/dephosphorylation of protein is dynamic in cells and the amount of phosphoproteins is low, the preservation of a phosphor group onto phosphosite throughout protein purification as well as enrichment of these phosphoproteins during purification has become a serious technical issue. To overcome difficulties commonly associated with phosphoprotein isolation, phosphopeptides' enrichment, and mass spectrometry analysis, we have developed a urea-based phosphoprotein purification protocol for plants, which instantly denatures plant proteins once the total cell content comes into contact with the UEB solution. To measure the alteration of phosphorylation on a phosphosite using mass spectrometer, an in vivo 15N metabolic labeling method (SILIA, i.e., stable isotope labeling in Arabidopsis) has been developed and applied for Arabidopsis differential phosphoproteomics. Thus far, hundreds of signaling-specific phosphoproteins have been identified using both label-free and 15N-labeled differential phosphoproteomic approach. The phosphoproteomics has allowed us to identify a number of signaling components mediating plant cell signaling in Arabidopsis. It is envisaged that a huge number of phosphosites will continue to be uncovered from phosphoproteomics in the near future, which will become instrumental for the development of plant phosphor-relay networks and molecular systems biology. © 2012 Springer Science+Business Media, LLC.

Courty P.,University of Victoria | Nasiry J.,Clear Technology
Production and Operations Management | Year: 2015

Buying frenzies caused by a firm's intentional undersupplying of a new product are frequently evident in several industries including electronics (cell phones, video games), luxury automobiles, and fashion goods. We develop a dynamic model of buying frenzies that incorporates the firm's manufacturing and sale of a product over time and characterizes the conditions under which inducing such frenzies is an optimal strategy. We find that buying frenzies occur when customers are sufficiently uncertain about their valuations of the product and when they discount the future sufficiently but not excessively. We propose measures of "customer desperation" and of the extent of scarcity to measure the depth and breadth of buying frenzies, respectively. We also demonstrate that such frenzies can have a significantly positive effect on firm profits and partially recover the loss due to non-commitment to future prices. This study provides managerial insights on how firms can influence market response to a new product through production, pricing, and inventory decisions to induce profitable frenzies. © 2015 Production and Operations Management Society.

Ye J.,CAS Wuhan Institute of Rock and Soil Mechanics | Wang G.,Clear Technology
Soil Dynamics and Earthquake Engineering | Year: 2015

Offshore structures, such as composite breakwaters, are generally vulnerable to strong seismic wave propagating through loose or medium-dense seabed foundation. However, the seismically induced failure process of offshore structures is not well understood. In this study, seismic dynamics of a composite breakwater on liquefiable seabed foundation is investigated using a fully coupled numerical model FSSI-CAS 2D. The computation results show that the numerical model is capable of capturing a variety of nonlinear interaction phenomena between the composite breakwater and its seabed foundation. The numerical investigation demonstrates a three-stage failure process of the breakwater under seismic loading. In this process, the far-field seabed can become fully liquefied first, inducing excessive settlement of the structure, followed by significant lateral movement and tilting of the structure when the near-field soil progressively liquefies. The study demonstrates great promise of using advanced numerical analysis in geotechnical earthquake design of offshore structures. © 2015 Elsevier Ltd.

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