Liu Q.,Sanda University |
Han L.,Shanghai Exit Entry Inspection and Quarantine Bureau |
Yi X.-H.,Shanghai Exit Entry Inspection and Quarantine Bureau |
Shi Y.-Y.,Shanghai Exit Entry Inspection and Quarantine Bureau |
And 5 more authors.
Journal of Chinese Mass Spectrometry Society | Year: 2014
A method for simultaneous detection of 2-alkylcyclobutanones was established by gas chromatography-triple quadrupole mass spectrometry (GC-QqQ-MS/MS). Samples were dissolved by n-hexane, purified by ProElut Silica extraction column. The results show that 2-dodecylcyclobutanone(2-DCB), 2-tetradecylcyclobutanone(2-TCB) are well separated from matrix interference peaks. The peak area against concentration shows good linear relationship in the concentration of 0.005-1.0 mg/L, the linear correlation coefficients (R2) are greater than 0.999. Addition of 0.01, 0.05 and 0.10 mg/kg levels of 2-DCB and 2-TCB in fat-containing function food products, the average recovery ranges from 85.6% to 97.1%, the relative standard deviations (RSDs) are less than 7.0 % (n=6), and the limit of quantification is 5 μg/kg. The method is simple, time-saving, high sensitivity and good stability for real samples analysis, which can provide a theoretical basis for the detection of irradiated markers in the fat-containing function food. ©, 2014, Chinese Society for Mass Spectrometry. All right reserved.