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A method for coating metallic surfaces of substrates with surfaces of aqueous coating) compositions in the form of a dispersion and/or a suspension containing at least one stabilized binder and a gelling agent, the cations having been dissolved out of the metallic surface of the substrate in a pretreatment stage and/or during the contacting. The invention further relates to such a coating based on an ionogenic gel, in which the coating is formed by a process further described herein.


The invention relates to a method for coating surfaces, to a corresponding coating, and to the use of the objects coated in accordance with said method. In accordance with the invention the object is achieved by a method for coating metallic surfaces of substrates that comprises or consists of the following steps: I) providing a substrate having a cleaned metallic surface, II) contacting and coating metallic surfaces with an aqueous composition in dispersion and/or suspension form, III) optionally rinsing the organic coating, and IV) drying and/or baking the organic coating or V) optionally drying the organic coating and coating it with a similar or further coating composition prior to drying and/or baking, characterized in that the coating in step II is carried out with an aqueous composition in dispersion and/or suspension form that comprises a complex fluoride, and at least one anionic polyelectrolyte is added to a nonionically or anionically/nonionically stabilized dispersion of film-forming polymers and/or to a suspension of film-forming inorganic particles and a coating forms that is based on an ionogenic gel comprising cations dissolved out of the metallic surface.


Patent
Nippon Paint Co. and Chemetall GmbH | Date: 2015-04-02

Disclosed is a composition for metal surface treatment which enables to form a chemical conversion coating film which achieves sufficient foundation surface concealment, coating adhesion and corrosion resistance. Also disclosed is a method for treating the surface of a metal material wherein such a composition for metal surface treatment is used. Specifically disclosed is a metal surface treatment composition used for a treatment of a metal surface, which composition contains a zirconium compound and/or a titanium compound, and a polyamine compound having a number average molecular weight of not less than 150 but not more than 500,000. The polyamine compound contains not less than 0.1 millimole but not more than 17 millimoles of a primary and/or secondary amino group per 1 g of the solid content, and the content of the zirconium compound and/or titanium compound in the metal surface treatment composition is not less than 10 ppm but not more than 10,000 ppm in terms of metal elements. The mass ratio of the zirconium element and/or titanium element contained in the zirconium compound and/or titanium compound relative to the polyamine compound is not less than 0.1 but not more than 100.


Patent
Chemetall GmbH | Date: 2015-08-19

An object of the present invention is to provide a surface treatment agent and a surface treatment method capable of imparting excellent corrosion resistance while enhancing adhesion between a surface of a metal substrate and a resin-containing layer. Disclosed is a surface treatment agent for treating a surface of a metal substrate, comprising: an acrylic resin having a carboxyl group and a hydroxyl group, an oxazoline group-containing compound and metal particles, wherein the metal particles are particles containing at least one metal selected from the group consisting of Nb, Ca and Nd. The metal particles are preferably in the form of a niobium oxide sol.


Patent
Chemetall GmbH | Date: 2015-02-03

The invention relates to a method for removing a substrate that is coated with an organic coated coating by means of ionogenic gel formation. In said method, a wet or dry organic coating that has not yet formed a film on the substrate is treated with an aqueous solution of a metal salt from main group I in the periodic table of the elements, a complexing agent and/or a basic compound having a pH value>10.


A chemical conversion treatment agent for surface treatment of a metal substrate, comprising:at least one metal element selected from the group consisting of zirconium, titanium, and hafnium;fluorine element; anda co-condensate of a silane coupling agent (A) and a silane coupling agent (B), whereinthe silane coupling agent (A) is a silane coupling agent having a tri- or di-alkoxysilane group and an amino group, andthe silane coupling agent (B) is a silane coupling agent represented by the following general formula (1):[Chem. 1]R represents an alkylene groups having 1 to 5 carbon atoms or the like,Z represents a cyclohexyl group optionally having an epoxy group or the like,a, b, and c each represent an integer of 0 to 3, provided that a sum of a, b, and c is 3, and a sum of a and b is 2 to 3, andx represents an integer of 1 to 3].


The invention relates to a method for coating metal surfaces with an acidic aqueous conversion composition which contains: in total 0.01 to 1 g/l of TiF_(6)^(2+), ZrF_(6)^(2+) and/or HfF_(6)^(2 )calculated as ZrF_(6)^(2+), 0 or 0.01 to 1 g/l in each case of Fe^(2+), Mn and/or Zn ions, of which at least one type of these ions is present in a content range from 0.01 to 1 g/l, 0 or 0.01 to 2 g/l of organic polymer and/or copolymer, 0 or 0.01 to 2 g/l of ultrafme particulate SiO_(2), approximately 0 or 0.01 to 10 g/l of at least one surfactant, approximately 0 or 0.05 to 10 g/l of anions of carbonate, nitrate and/or sulphate, and 0 or 0.001 to 2 g/l of carboxylate and/or sulphonate anions, wherein the content of molybdate and/or of P-containing oxy anions is in each case <0.1 g/l or is approximately 0 g/l, and wherein the composition has a pH value in the range from 2.5 to 6.5. The invention also relates to a corresponding coating and to the use of the substrates coated in this way.


A method for coating a metallic surface with an aqueous composition for pretreating before applying another coating or for treating said metallic surface. In addition to water, the composition contains: a) at least one hydrolyzable or at least partially hydrolyzed silane; b) at least one metal chelate; c) at least one organic film former, and; d) at least one long-chain alcohol that serves as a film forming aid. The unsoiled, scoured, cleaned and/or pretreated metallic surface is brought into contact with the aqueous composition so that a film forms on the metallic surface, which is subsequently dried, compacted in part or completely by film formation and, if necessary, additionally hardened. The dried and, if necessary, additionally hardened film has a layer thickness ranging from 0.01 to 10 m. The invention also relates to corresponding aqueous compositions.


A method for the electroless coating of surfaces of articles and particles with a multiplicity of inorganic and organic water-insoluble particles to form a substantially flush-resistant layer of high particle density, in which the particles are applied to the surfaces to be coated in an aqueous composition that can be stabilized or is stable, in the form of a dispersion, and are applied to the surface to be coated substantially or predominantly by electrostatic forces and are applied to and secured on the surfaces to be coated substantially or predominantly by electrostatic forces. The surfaces to be coated are first activated by an activating agent, wherein an activation layer with charges is formed by the activating agent on the surfaces to be coated.


Mixtures of low-acid lithium borate salts and lithium hydride, methods for producing the same and the use thereof for battery electrolytes.

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