Centro Nacional Del Hidrogeno

Puertollano, Spain

Centro Nacional Del Hidrogeno

Puertollano, Spain

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Vyhmeister E.,University las Fuerzas Armadas | Aleixendri Munoz C.,Bound | Bermudez Miquel J.M.,Bound | Pina Moya J.,Bound | And 7 more authors.
Journal of Cleaner Production | Year: 2017

The productivity of the mining industry in Chile, currently the main driver of Chilean economy, is closely tied to foreign demand for ores. Ore-processing is known for involving energy–intensive processes, such as comminution, concentrating and cathodic processes. As mining activities take place in the arid north of Chile, they are affected by water scarcity. Water shortage has forced the industry to pump desalinated seawater up to mining sites over 2000 m above sea level, further increasing electricity consumption. Given these energy needs, and the fact that electrical energy supply in the north of Chile is based on fossil fuels, it is important to consider the use of renewable energies as environment-friendly and economic alternatives. The aim of this work is to evaluate, by an optimized techno-economic analysis, the use of photovoltaic and a novel wind-based technology to supply at least 10% of the current and the predicted electrical energy requirements of the mining industry in the Antofagasta region. A combination of an optimization problem and technical evaluation was performed using Matlab to obtain the optimal number of solar and wind-based technology units in a case study. Total energy generation from a novel wind-based technology unit is 67,616 MWh/y, corresponding to 14.45·106 Nm3 (1298 t) of hydrogen and 7.41·106 Nm3 (10,323 t) of oxygen after electrolytical transformation. Considering a 65% efficiency of the combined cycle fed with hydrogen and oxygen, 28,133 MWh/y of electrical energy would be obtained. For the cases studied the cost of energy from the combined system was estimated to be between 0.255 US$/kWh and 0.273 US$/kWh, slightly higher than the average energy regional cost. According to the analysis, the renewable energy system could be a sustainable alternative to supply economic green energy to the mining industry in Chile. © 2017 Elsevier Ltd


Bordons C.,University of Seville | Garcia-Torres F.,Centro Nacional Del Hidrogeno | Valverde L.,University of Seville
RIAI - Revista Iberoamericana de Automatica e Informatica Industrial | Year: 2015

This paper deals with some issues related to optimal operation of microgrids, which are a group of loads, generators and energy storage systems that can be managed isolated or connected to the main grid, in a coordinated way in order to reliably supply electricity. The control problems and solution are addressed both for optimal dispatch and for the integration of the microgrid in the electricity market. Development of Model Predictive Controllers are presented for case studies that include several renewable sources (photovoltaic and wind) as well as hybrid storage using hydrogen. Some experimental results for a demonstration microgrid are presented, as well as simulations of scheduling in the electricity market. The results indicate that development of the appropriate controllers will allow a competitive participation of renewable energy in the new model of the electrical system. © 2014 CEA. Publicado por Elsevier España, S.L.U. Todos los derechos reservados.


Garcia-Torres F.,Centro Nacional Del Hidrogeno | Bordons C.,Universidad Politécnica de Ingeniería | Vazquez S.,Universidad Politécnica de Ingeniería
Proceedings of the IEEE International Conference on Industrial Technology | Year: 2015

Microgrids appear as a key-solution to manage smart grids with high penetration of renewable energy generation and non-linear and unbalanced loads. Their flexibility allows the energy exchange with the utility network in grid-connected mode or the transition to an islanded operation mode from the main grid in case of disturbances or faults. While in grid-connected mode the main grid imposes the frequency and voltage, in the islanded mode the own microgrid must do the load balance between all the connected components to the microgrid and must supervise that the power flow inside the microgrid is done according to the power quality levels that all the devices of the microgrid require. In order to improve the power quality in these kind of applications, a novel control strategy based on Model Predictive Control (MPC) and Fourier analysis is presented in this paper applied to the voltage/frequency control of a Voltage Source Inverter (VSI). At each sample instant, the current demand in the microgrid is predicted through the estimation of the equivalent Thevenin's impedance in the microgrid. This fact allows the inverter controller to select the most appropriate gate-signal combination to maintain the reference frequency and the voltage in the microgrid. © 2015 IEEE.


Amores E.,Centro Nacional Del Hidrogeno | Rodriguez J.,Centro Nacional Del Hidrogeno | Carreras C.,Centro Nacional Del Hidrogeno
International Journal of Hydrogen Energy | Year: 2014

In order to improve the production of environmental friendly hydrogen, new advanced alkaline electrolyzers must be designed to optimize their combination with renewable energies. In pursuing this goal, modeling of alkaline electrolyzers becomes a powerful design tool. In this paper is presented a mathematical model that describes the behavior of an alkaline electrolysis cell. Unlike most of the existing models in literature, the proposed model simulates the influence of both electrode/diaphragm distance and electrolyte concentration in regular operation. The role of these aspects is crucial when designing alkaline electrolyzers since the process efficiency is found to be very sensitive to them. The computations done with the model presented here were validated with in situ experimental data, reporting a great accuracy: the maximum error was around 1% from all polarization curves studied. Combination with renewable energies was also studied by introducing a solar PV profile and the error reported never exceeds 3%. The influence of the considered variables (temperature, electrode/diaphragm distance and electrolyte concentration) was quantified using sensitivity analysis. © 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.


Nieto B.,Centro Nacional Del Hidrogeno | Manjavacas G.,Centro Nacional Del Hidrogeno | Merino C.,Centro Nacional Del Hidrogeno | Quintana R.,Centro Nacional Del Hidrogeno
International Journal of Hydrogen Energy | Year: 2014

Hydrogen, within the so called Hydrogen Economy, has the potential to become the energy carrier of the future which could change entirely the energy industry. It could help to change to a more reliable, efficient and environmentally friendly energy sector. Hydrogen Economy is based on different technologies which are related to the scientific and industrial sectors. Thus, all equipment included within hydrogen technologies are in an experimental stage or in a too early market, safety being one of the research lines followed in the design and use of these equipment and devices. This paper includes the design and implementation of different building works to have a place to operate in a safe way electrolyzers and fuel cell systems that belong to a research project in which Centro Nacional del Hidrógeno (CNH2) is taking part in its current facilities. Because of working with hydrogen, the whole design was considered from the point of view of the potential to generate explosive atmospheres. Copyright © 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.


Garcia F.,Centro Nacional Del Hidrogeno | Bordons C.,Universidad Politécnica de Ingeniería
IECON Proceedings (Industrial Electronics Conference) | Year: 2013

The transition from the current power system to a renewable energy-based smart grid will require of smaller units for managing the random aspects between the generation sources and load demand. The introduction of energy storage systems inside microgrids brings the opportunity to decide the optimal moment to purchase or sale energy to the grid. The use of different energy storage systems gives the chance to take the advantages of each system minimizing the disadvantages. © 2013 IEEE.


Deleebeeck L.,Technical University of Denmark | Gil V.,Technical University of Denmark | Ippolito D.,Technical University of Denmark | Campana R.,Centro Nacional del Hidrogeno | And 2 more authors.
ECS Transactions | Year: 2015

Hybrid direct carbon fuel cells employ a classical solid oxide fuel cell together with carbon dispersed in a carbonate melt on the anode side. In a European project, the utilization of various coals has been investigated with and without addition of an oxidation catalyst to the carbon-carbonate slurry or anode layer. The nature of the coal affects both open circuit voltage and power output. Highest OCV and power densities were observed for bituminous coal and by adding manganese oxide or praseodymium-doped ceria to the carbon/carbonate mixture. Comparing the carbon black fueled performance of an anode supported (315 μm anodes) and cathode supported cell (15 μm anode) indicates a superior performance of the latter. Using un-catalyzed biomass (charcoal) as fuel results in an OCV of 941 mV and a maximum power density of 78 mW/cm2 at 755°C similar to the power output of manganese oxide catalyzed bituminous coal (73 mW/cm2). © The Electrochemical Society.


There are currently two technologies that dominate the current trends of electric vehicles: fuel cell and battery. Both options generate electricity to drive electric motors, eliminate pollution and improve vehicle effi ciency. Fuel cells derive their energy from hydrogen stored in the vehicle, while the batteries get the energy from grid. The two forms of electricity generation have advantages and disadvantages in terms of power density and energy density, dynamic response, refueling time, autonomy and the possibility of regenerative braking, infrastructure for recharging. The electric vehicle confi guration will consist of a series of blocks that must give the system a performance similar to the conventional confi guration in the same terms of speed, acceleration, time of refueling and comfort. This paper develops the analysis of current technology in the propulsion system of electric vehicles for further optimal sizing of components and systems that make the same fundamental, a study of the most appropriate for the use of either technology.


Rodriguez J.,Centro Nacional del Hidrogeno | Rojas N.,Centro Nacional del Hidrogeno | Sanchez-Molina M.,Centro Nacional del Hidrogeno | Rodriguez L.G.,Centro Nacional del Hidrogeno | And 2 more authors.
Chemical Engineering Transactions | Year: 2016

Proton exchange membrane fuel cells (PEMFCs) are a class of low temperature fuel cells characterized by a high energy density, good compatibility with the environment and a wide variety of applications. In this work, four hybrid membranes organic-inorganic based on Nafion [Nafion-TiO2, Nafion-ZrO2, Nafion-(TiO2-ZrO2) and Nafion-YSZ] have been fabricated and evaluated in order to be used as electrolytes in intermediate temperature proton exchange membrane fuel cells (IT-PEMFCs). Doctor Blade technique has been the method used to fabricate these membranes since it simplifies the synthesis and scale-up of hybrid films. Thereby, very homogeneous nanocomposite membranes with high reproducibility, low thicknesses and large size have been easily obtained. The hybrid membranes have been evaluated in terms of water uptake and further characterized by thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). Finally, the hybrid membranes were used in the fabrication of membrane-electrode assemblies (MEAs), placed in single cells, and tested in operating conditions. In this study the method for films preparation has been improved and the presented results allowed to identify the membranes with the best performance and potential applicability as electrolytes in IT-PEMFCs. Copyright © 2016, AIDIC Servizi S.r.l.

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