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Semard G.,Cirsee Center International Of Recherche Sur Leau Et Lenvironnement | Semard G.,CNRS Separative Sciences and Methods | Peulon-Agasse V.,CNRS Separative Sciences and Methods | Bruchet A.,Cirsee Center International Of Recherche Sur Leau Et Lenvironnement | And 2 more authors.
Journal of Chromatography A | Year: 2010

It is important to develop methods of optimizing the selection of column sets and operating conditions for comprehensive two-dimensional gas chromatography. A new method for the calculation of the percentage of separation space used was developed using Delaunay's triangulation algorithms (convex hull). This approach was compared with an existing method and showed better precision and accuracy. It was successfully applied to the selection of the most convenient column set and the geometrical parameters of second column for the analysis of 49 target compounds in wastewater. © 2010 Elsevier B.V.

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