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Granstrom J.,Mitsubishi Chemical Center For Advanced Materials | Granstrom J.,Center for Polymers and Organic Solids | Roy A.,Center for Polymers and Organic Solids | Rowell G.,University of California at Santa Barbara | And 4 more authors.
Thin Solid Films | Year: 2010

We present a general method for making thin and smooth films of a water-repelling perfluorinated polymer. These films function as encapsulation barrier layers against water and oxygen permeation. Based on a phenomenological analysis, we find that disturbances in flow due to the Rayleigh-Benard-Marangoni instability during drying of spin-cast perfluorinated polymer films cause high surface roughness and the formation of "pinholes". Atomic force microscopy measurements show that this instability can increase the surface roughness by an order of magnitude. Casting films from solutions with higher polymer concentration and from solvents with higher viscosity suppress the instability and significantly reduce the roughness. Suppression of the instability results in improved barrier properties as indicated by the calcium thin film optical transmission test. © 2009 Elsevier B.V. All rights reserved.


News Article | December 6, 2016
Site: www.cemag.us

With a new technique for manufacturing single-layer organic polymer solar cells, scientists at UC Santa Barbara and three other universities might very well move organic photovoltaics into a whole new generation of wearable devices and enable small-scale distributed power generation. The simple doping solution-based process involves briefly immersing organic semiconductor films in a solution at room temperature. This technique, which could replace a more complex approach that requires vacuum processing, has the potential to affect many device platforms, including organic printed electronics, sensors, photodetectors and light-emitting diodes. The researchers’ findings appear in the journal Nature Materials. “Because the new process is simple to use, general in terms of applicability and should be configurable into mass productions, it has the potential to greatly accelerate the widespread implementation of plastic electronics, of which solar cells are one example,” says co-author Guillermo Bazan, director of UCSB’s Center for Polymers and Organic Solids. “One can see impacts in technologies ranging from light-emitting devices to transistors to transparent solar cells that can be incorporated into building design or greenhouses.” Studied in many academic and industrial laboratories for two decades, organic solar cells have experienced a continuous and steady improvement in their power conversion efficiency with laboratory values reaching 13 percent compared to around 20 percent for commercial silicon-based cells. Though polymer-based cells are currently less efficient, they require less energy to produce than silicon cells and can be more easily recycled at the end of their lifetimes. This new method, which provides a way of inducing p-type electrical doping in organic semiconductor films, offers a simpler alternative to the air-sensitive molybdenum oxide layers used in the most efficient polymer solar cells. Thin films of organic semiconductors and their blends are immersed in polyoxometalate solutions in nitromethane for a brief time — on the order of minutes. The geometry of these new devices is unique as the functions of hole and electron collection are built into the light-absorbing active layer, resulting in the simplest single-layer geometry with few interfaces. “High-performing organic solar cells require a multiple layer device structure,” says co-author Thuc-Quyen Nguyen, a professor in UCSB’s Department of Chemistry and Biochemistry. “The realization of single-layer photovoltaics with our approach will simplify the device fabrication process and therefore should reduce the cost. The initial lifetime testing of these single layer devices is promising. This exciting development will help transform organic photovoltaics into a commercial technology.” Organic solar cells are unique within the context of providing transparent, flexible and easy-to-fabricate energy-producing devices. These could result in a host of novel applications, such as energy-harvesting windows and films that enable zero-cost farming by creating greenhouses that support crops and produce energy at the same time. Additional contributors to the research include Ming Wang of UCSB; Samuel Graham, Bernard Kippelen and Seth Marder of the Georgia Institute of Technology; Naoya Aizawa of Kyushu University in Japan; and Alberto Perrotta of Eindhoven University of Technology in the Netherlands. The work was funded in part by a Department of the Navy, Office of Naval Research Award, through the MURI Center CAOP, Office of Naval Research Award, and by the Department of Energy through the Bay Area Photovoltaic Consortium.


News Article | December 5, 2016
Site: www.eurekalert.org

With a new technique for manufacturing single-layer organic polymer solar cells, scientists at UC Santa Barbara and three other universities might very well move organic photovoltaics into a whole new generation of wearable devices and enable small-scale distributed power generation. The simple doping solution-based process involves briefly immersing organic semiconductor films in a solution at room temperature. This technique, which could replace a more complex approach that requires vacuum processing, has the potential to affect many device platforms, including organic printed electronics, sensors, photodetectors and light-emitting diodes. The researchers' findings appear in the journal Nature Materials. "Because the new process is simple to use, general in terms of applicability and should be configurable into mass productions, it has the potential to greatly accelerate the widespread implementation of plastic electronics, of which solar cells are one example," said co-author Guillermo Bazan, director of UCSB's Center for Polymers and Organic Solids. "One can see impacts in technologies ranging from light-emitting devices to transistors to transparent solar cells that can be incorporated into building design or greenhouses." Studied in many academic and industrial laboratories for two decades, organic solar cells have experienced a continuous and steady improvement in their power conversion efficiency with laboratory values reaching 13 percent compared to around 20 percent for commercial silicon-based cells. Though polymer-based cells are currently less efficient, they require less energy to produce than silicon cells and can be more easily recycled at the end of their lifetimes. This new method, which provides a way of inducing p-type electrical doping in organic semiconductor films, offers a simpler alternative to the air-sensitive molybdenum oxide layers used in the most efficient polymer solar cells. Thin films of organic semiconductors and their blends are immersed in polyoxometalate solutions in nitromethane for a brief time -- on the order of minutes. The geometry of these new devices is unique as the functions of hole and electron collection are built into the light-absorbing active layer, resulting in the simplest single-layer geometry with few interfaces. "High-performing organic solar cells require a multiple layer device structure," said co-author Thuc-Quyen Nguyen, a professor in UCSB's Department of Chemistry and Biochemistry. "The realization of single-layer photovoltaics with our approach will simplify the device fabrication process and therefore should reduce the cost. The initial lifetime testing of these single layer devices is promising. This exciting development will help transform organic photovoltaics into a commercial technology." Organic solar cells are unique within the context of providing transparent, flexible and easy-to-fabricate energy-producing devices. These could result in a host of novel applications, such as energy-harvesting windows and films that enable zero-cost farming by creating greenhouses that support crops and produce energy at the same time. Additional contributors to the research include Ming Wang of UCSB; Samuel Graham, Bernard Kippelen and Seth Marder of the Georgia Institute of Technology; Naoya Aizawa of Kyushu University in Japan; and Alberto Perrotta of Eindhoven University of Technology in the Netherlands. The work was funded in part by a Department of the Navy, Office of Naval Research Award, through the MURI Center CAOP, Office of Naval Research Award and by the Department of Energy through the Bay Area Photovoltaic Consortium.


News Article | January 26, 2016
Site: news.yahoo.com

Giant clams reflect white by mixing colors, much like how video displays combine red, green and blue pixels. Here is an example of a giant clam reflecting bright blue. More Iridescent cells in the flesh of giant clams could one day help scientists design more efficient solar panels, and television and smartphone screens that are easier on the eyes, researchers say. Giant clams are native to coral reefs of the Pacific and Indian oceans and can live up to 100 years in the wild. Although they live in nutrient-poor water, they can grow up to 47 inches (120 centimeters) long because of symbiotic photosynthetic algae — the clams absorb nutrients the algae generate, while the algae live off nitrogen-rich waste from the clams, previous research found. In a new study, scientists focused on iridescent cells in the exposed flesh of the clams. These cells, known as iridocytes, generate a dazzling array of colors, including blues, greens, golds and, more rarely, white. [Biomimicry: 7 Clever Technologies Inspired by Nature] "We are studying the clams to see how their iridescent cells interact with the algae to enhance photosynthesis,"study lead author Amitabh Ghoshal, an optical physicist at the University of California, Santa Barbara, said in a statement. "Like solar cells, photosynthesis involves converting light into energy. As we expand our understanding of the clam's system for light collection, we can take the lessons from it to create solar cells that more efficiently convert light to energy." The researchers are systematically investigating each color the clams produce to understand the mechanisms involved in producing the color and its biological significance. To learn more about the white color, the scientists analyzed live giant clams of the species Tridacna maxima and Tridacna derasa. Surprisingly, both clam species create their white hue by mixing colors together much like video displays mix red, blue and green pixels to make white. "We have discovered a new way that animals — in this case, the giant clam — makes white color," Ghoshal told Live Science. "Most white coloration in animals is produced either by micron-sized spheres or lumps, which is similar to how paint looks white, or by reflective structures that have a largely varying spacing between them, which allow for reflecting visible light of a broad range of colors." In addition, the researchers discovered that the two species of giant clams employed different methods for mixing colors to produce white. In Tridacna maxima, white comes from tight clusters of differently colored iridocytes. In Tridacna derasa, white results from iridocytes that are each multicolored and look white from a distance. Most of today's video displays rely on light sources such as LEDs, while giant clams only need sunlight. The iridocytes of the mollusks contain tiny multilayer structures of proteins that act like mirrors to reflect different colors of light, the researchers said. If the researchers can create and control structures similar to those that generate color in the clams, it might be possible to build color-reflective displays that work with ambient light sources such as sunlight or normal indoor lighting, Ghoshal said. "Producing color the way giant clams do could lead to smartphone, tablet and TV screens that use less power and are easier on the eyes," Ghoshal said in a statement. In addition, the researchers want to see if structures like those found in giant clams might improve the efficiency of solar cells. "If we could use what we learned from the clams to build a very efficient distributed light-gathering system, then we could use that to make more efficient 3D solar cells that require less area than our present rooftop and land-based solar farms," Ghoshal said in a statement. The scientists are currently collaborating with Guillermo Bezan, director of the Center for Polymers and Organic Solids at the University of California, Santa Barbara, to design and test solar cells inspired by clams. Ghoshal and colleagues Elizabeth Eck and Daniel Morse at the University of California, Santa Barbara, detailed their findings Jan. 19 in the journal Optica. Copyright 2016 LiveScience, a Purch company. All rights reserved. This material may not be published, broadcast, rewritten or redistributed.


Brunetti F.G.,University of California at Santa Barbara | Kumar R.,Center for Polymers and Organic Solids | Wudl F.,University of California at Santa Barbara | Wudl F.,Center for Polymers and Organic Solids
Journal of Materials Chemistry | Year: 2010

The past ten years have witnessed the development of bulk-heterojunction (BHJ) solar cells, which have emerged as an attractive renewable energy source in response to rising energy costs and environmental pollution. In such a solar cell, charge transfer at the donor-acceptor interface is a crucial aspect that significantly affects overall device efficiency. Therefore, the choice of these two components and their design are important factors for the optimization of plastic solar cells (PSCs). This feature article correlates the performance of the device to the active layer composites, analyzing the motivations behind specific BHJ designs. Several low-bandgap polymers are described based on their different donor-acceptor units and their influence on both the optical absorption and the electrochemical properties. As for the accepting materials, we examine the effect of chemical functionalization in a series of fullerene derivatives, carbon nanotubes and non-fullerene based compounds on their performances in PSCs. The understanding of film-morphology control is also briefly discussed. © The Royal Society of Chemistry.

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