Tong L.,Chongqing University |
Chen J.,Chongqing University |
Yuan Y.,Chongqing University |
Cui Z.,Chongqing University |
And 6 more authors.
Journal of Applied Polymer Science
A novel Pb(II) ion-imprinted chelating nanofibers (nIIP), synthesized by combining electrospinning with surface ion imprinting technique, was reported in this study. nIIP was characterized with Fourier transmission infrared spectrometry and scanning electron microscopy, respectively. The performance of nIIP for Pb(II) sorption was conducted through a batch adsorption experiments. Experimental data showed that adsorption capacity of nIIP was much higher than that of non-ion imprinted chelating acrylic microfibers (mNIP) derived from commercial available acrylic microfibers, and adsorption behaviors agreed well with pseudo-second-order kinetic and Langmuir isotherm model. The values of Gibbs free energy change derived from experimental data suggested that the adsorption Pb(II) on nIIP is spontaneous and favorable at high temperature. In addition, nIIP had the highest selectivity among three tested fibrous adsorbents for Pb(II) from binary metal solution, the selectivity coefficients for Pb(II) from binary metal solution of Pb(II)/Cu(II), Pb(II)/Ni(II), and Pb(II)/Cd(II) onto nIIP were 47, 101, and 162, respectively. Besides, a forty adsorption/desorption cycles revealed that nIIP was a promising recyclable adsorbent. In conclusion, the novel nIIP is a highly effective adsorbent for enrichment and separation of Pb(II) in the presence of competitive ions in aqueous solution, and it is potential to be applied for recovering metals from heavy metal polluted industrial wastewater such as Pb(II)/Cd(II), Pb(II)/Ni(II), and Pb(II)/Cu(II) polluted wastewater. © 2014 Wiley Periodicals, Inc. Source
Zhang Q.,Chongqing University |
Liu L.,Chongqing University |
Liu Y.-C.,Chongqing University |
Zhang C.,Chongqing University |
And 4 more authors.
Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
Polyvinyl alcohol/polyetherimide(PVA/PEI) nanofibers were fabricated by electrospinning. Subsequently, the nanofibers were functionalized with carbon disulfide to form polyvinyl alcohol/dithiocarbamates(PVA/DTC) nanofibers with higher adsorption capacity for heavy metal ions. The adsorption performance of PVA/DTC nanofibers for lead as well as the crosslinking and functionalization reaction PVA/PEI were investigated. The experimental data show that the fibers have diameters in hundreds nanometers and good appea-rance. The microstructure of nanofiber almost kept unchanged after crosslinking process and functionalization. The PVA/DTC nanofibers with good regeneration power possess much rapid adsorption and higher adsorption capacity. It is potential adsorption material for efficently removal heavy metal ions from waste water. Source