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Zhu J.,Beijing Key Laboratory Of Fine Ceramicsstate Key Laboratory Of New Ceramics And Fine Processinginstitute Of Nuclear And New Energy Technologytsinghua Universitybeijing100084Pr China | Zhang Y.,Beijing Key Laboratory Of Fine Ceramicsstate Key Laboratory Of New Ceramics And Fine Processinginstitute Of Nuclear And New Energy Technologytsinghua Universitybeijing100084Pr China | Song X.,Beijing Key Laboratory Of Fine Ceramicsstate Key Laboratory Of New Ceramics And Fine Processinginstitute Of Nuclear And New Energy Technologytsinghua Universitybeijing100084Pr China | Zhang Q.,Beijing Key Laboratory Of Fine Ceramicsstate Key Laboratory Of New Ceramics And Fine Processinginstitute Of Nuclear And New Energy Technologytsinghua Universitybeijing100084Pr China | And 2 more authors.
Physica Status Solidi (A) Applications and Materials Science | Year: 2015

The sol-gel processing, microstructures, dielectric properties and energy-storage properties of barium strontium titanate glass-ceramics over the sintering temperature range of 1000-1150°C were studied. Through the X-ray diffraction result, it is revealed that the crystallinity increases as the sintering temperature increased from 1000 to 1080°C and has reached a steady-state regime above 1100°C. Scanning electron microscopy images showed that with the increase of sintering temperature, the crystal size increased. Dielectric measurements revealed that the increase in the sintering temperature resulted in a significant increase in the dielectric constant, a strong sharpness of the temperature-dependent dielectric response and a pronounced decrease of the temperature of the dielectric maximum. The correlation between charge spreading behavior and activation energies of crystal and glass was discussed by the employment of the impedance spectroscopy studies. As a result of polarization-electric field hysteresis loops, both the charged and discharged densities increased with increasing sintering temperature. And the maximum value of energy storage efficiency was found to occur at 1130°C. Finally, the dependence of released energy and power densities calculated from the discharged current-time (I-t) curves on the sintering temperature was studied. The relationship between the energy storage properties and microstructure was correlated. Polarization-electric field hysteresis loops for the BST glass-ceramics sintered at different temperatures. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Loading Beijing Key Laboratory Of Fine Ceramicsstate Key Laboratory Of New Ceramics And Fine Processinginstitute Of Nuclear And New Energy Technologytsinghua Universitybeijing100084Pr China collaborators
Loading Beijing Key Laboratory Of Fine Ceramicsstate Key Laboratory Of New Ceramics And Fine Processinginstitute Of Nuclear And New Energy Technologytsinghua Universitybeijing100084Pr China collaborators