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Matsuoka K.,Area for Molecular Function | Yamaguchi H.,Area for Molecular Function | Koyama T.,Area for Molecular Function | Hatano K.,Area for Molecular Function | Terunuma D.,Area for Molecular Function
Tetrahedron Letters

Synthetic construction of fucosyl chitobiose [GlcNAcβ1→4(Fucα1→3)GlcNAc] as an allergy-associated carbohydrate epitope was accomplished from three building blocks. The trisaccharidic unit was further transformed into a carbohydrate monomer and polymerization of the glycomonomer proceeded smoothly to provide a series of glycopolymers having various carbohydrate densities. In addition to the organic syntheses, biological evaluations of the glycomonomer and the polymers were carried out and sugar-clustering effects were observed. © 2010 Elsevier Ltd. All rights reserved. Source

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