Santiago del Estero, Argentina
Santiago del Estero, Argentina

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Martin-Zarco M.,Area de Quimica Organica | Rodriguez-Lopez J.,Area de Quimica Organica
Journal of Polymer Science, Part A: Polymer Chemistry | Year: 2015

A new sulfonated dendrimer with an arylene ether sulfone backbone has been synthesized, fully characterized, and blended with PBIOO® to prepare acid-base proton-conducting membranes under different conditions and with different composition ratios. Water-soluble sulfonated hyperbranched polyglycerols of different molecular weights were also used as the acidic components. Membrane properties such as ion-exchange capacity, water uptake, thermal stability, proton conductivity, and morphology have been studied and discussed. The nature of the acidic component and the morphology of the membranes had a marked influence on the final properties. © 2015 Wiley Periodicals, Inc.

Mancini P.M.E.,Area de Quimica Organica | Rosa C.D.D.,Area de Quimica Organica | Ormachea C.M.,Area de Quimica Organica | Ormachea C.M.,CONICET | And 3 more authors.
RSC Advances | Year: 2013

The reactions between 1-nitronaphthalene 1 and two nucleophilic dienes, Danishefskýs diene 2 and 1-trimethylsilyloxy-1,3-butadiene 3, to yield phenanthrenols 7 and 8 developed in protic and aprotic ionic liquids (ILs) with an imidazolium cation base permit to conclude that the reactions occur in better experimental conditions than in molecular solvents. The yields obtained with protic ILs are better than those observed with aprotic ILs. In this sense, the higher yields obtained with aprotic ILs, (working at 60°C, 48 h) are comparable with the lower yields observed in protic ILs (60°C, 24 h). DFT calculations for the reaction of 1-nitronaphthalene 1 with diene 3, in the absence and in the presence of tetrafluoroborate of 1-metilimidazolium [HMIM][BF4] as protic ILs, indicate that this reaction is a domino process that comprises two consecutive processes: i) a polar Diels-Alder (P-DA) reaction between 1 and 3, and ii) an elimination of nitroso acid 5 to yield dihydrophenanthrene 11. Thermodynamic calculations indicate that while the first reaction is the rate-determining step of this domino process, the nitroso acid elimination is the driving force responsible for the formation of dihydrophenanthrene 11. Implicit and explicit solvent effects indicate that while the hydrogen bond formation between HMIM and one oxygen atom of the nitro groups favour the two reactions, implicit solvent effects modelled by PCM decelerate the P-DA reaction by a large solvation of reagents. Finally, DFT analysis of reagents offers an explanation of the catalytic role of protic ILs in these P-DA reactions. © 2013 The Royal Society of Chemistry.

Della Rosa C.D.,Area de Quimica Organica | Mancini P.M.E.,Area de Quimica Organica | Kneeteman M.N.,Area de Quimica Organica | Lopez Baena A.F.,Area de Quimica Organica | And 2 more authors.
Journal of Molecular Structure | Year: 2014

The reactions between 2- and 3-nitrobenzothiophenes with three dienes of different nucleophilicity, 1-methoxy-3-trimethylsilyloxy-1,3-butadiene, 1-trimethylsilyloxy-1,3-butadiene and isoprene developed in anhydrous benzene and alternative under microwave irradiation with molecular solvents or in free solvent conditions, respectively, for produce dibenzothiophenes permit to conclude that both nitroheterocycles act as electrophile with the cited dienes. In the cases of the dienes 1-methoxy-3-trimethylsilyloxy-1,3-butadiene and 1-trimethylsilyloxy-1,3-butadiene which posses major nucleophilicity the observed product is the normal cycloaddition one. However when the diene is isoprene the product with both electrophiles follow the hetero Diels-Alder way. These reactions are considered polar cycloaddition reactions and the yields are reasonables. Moreover the polar Diels-Alder reactions of nitrobenzothiophenes with electron rich dienes 1-trimethylsilyloxy-1,3-butadiene have been theoretically studied using DFT methods. © 2014 Published by Elsevier B.V.

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