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Syracuse, NY, United States

Amidon T.E.,Applied Biorefinery science LLC | Bujanovic B.,SUNY ESF | Liu S.,SUNY ESF | Hasan A.,SUNY ESF | Howard J.R.,Applied Biorefinery science LLC
RSC Green Chemistry | Year: 2013

It is virtually axiomatic that increased value can be generated by isolating relatively pure substances from heterogeneous raw materials. Woody biomass has been widely used throughout the world to supply resources to fulfill human needs, however, the whole raw material has not necessarily been utilized efficiently. Traditional wood fractioning techniques targeted cellulose as the end product, while discarding or destroying much of the other potential value. The world's population has more than doubled to over 7.25 billion over the past 50 years. If we wish to achieve long-term sustainability for humans on Earth, such wasteful practices need to be replaced or modified to more efficiently utilize available resources. One means for contributing to that goal is to develop processes that recover a larger portion of the raw material in a broader portfolio of products. Applied Biorefinery Sciences, LLC is commercializing a value-optimization pathway (ABS Processt BT) for generating a multiproduct portfolio by isolating and recovering higher total yield and value from woody biomass. By more efficiently fractionating woody biomass into usable products, ABS Processt BT creates a previously unavailable, economically viable niche position for capturing sustainable, renewable value. © 2013 The Royal Society of Chemistry.

Amidon T.E.,Applied Biorefinery science LLC | Amidon T.E.,SUNY College of Environmental Science and Forestry | Bujanovic B.,SUNY College of Environmental Science and Forestry | Liu S.,SUNY College of Environmental Science and Forestry | Howard J.R.,Applied Biorefinery science LLC
Forests | Year: 2011

While there may be many reasons why very interesting science ideas never reach commercial practice, one of the more prevalent is that the reaction or process, which is scientifically possible, cannot be made efficient enough to achieve economic viability. One pathway to economic viability for many business sectors is the multi-product portfolio. Research, development, and deployment of viable biorefinery technology must meld sound science with engineering and business economics. It is virtually axiomatic that increased value can be generated by isolating relatively pure substances from heterogeneous raw materials. Woody biomass is a heterogeneous raw material consisting of the major structural components, cellulose, lignin, and hemicelluloses, as well as minor components, such as extractives and ash. Cellulose is a linear homopolymer of D-glucopyrano-units with β-D(1→4) connections and is the wood component most resistant to chemical and biological degradation. Lignin is a macromolecule of phenylpropanoid units, second to cellulose in bio-resistance, and is the key component that is sought for removal from woody biomass in chemical pulping. Hemicelluloses are a collection of heteropolysaccharides, comprised mainly of 5- and 6-carbon sugars. Extractives, some of which have high commercial value, are a collection of low molecular weight organic and inorganic woody materials that can be removed, to some extent, under mild conditions. Applied Biorefinery Sciences, LLC (a private, New York, USA based company) is commercializing a value-optimization pathway (the ABS Process™) for generating a multi-product portfolio by isolating and recovering homogeneous substances from each of the above mentioned major and minor woody biomass components. The ABS Process™ incorporates the patent pending, core biorefinery technology,"hot water extraction", as developed at the State University of New York College of Environmental Science and Forestry (SUNY-ESF). Hot water extraction in the absence of mineral acids and bases is preferred because of its ability to generate multiple high value output products without chemical input, recovery, or disposal costs. Instead of added chemicals in the cooking phase, the ABS Process™ relies upon an autocatalytic reaction in which acetyl groups, bound through an ester linkage to hemicellulose chains, are hydrolyzed at high temperature in water. The resulting acidic conditions (final pH ~3.5) and temperatures of 160-170°C permit further solubilization and diffusion of oligomeric 5- and 6-carbon sugars, acetic acid, aromatic substances, monomeric sugars, and other trace compounds into the extract solution. These conditions also avoid extensive degradation of monosaccharides, enabling membrane fractionation and other chemical separation techniques to be used in the following separations. A range of separation techniques are applied on the extract solution to isolate and purify fermentable sugars, acetic acid, lignin, furfural, formic acid, other hemicellulose related compounds, lignin, lignin degradation products, and phenolic extractives for commercial sale. The extracted lignocellulosic biomass, with reduced hemicellulose content and is thus less heterogeneous, carries the value-added advantages of: (1) enhanced product characteristics, and (2) reduced energy and chemical manufacturing costs. Thus, by fractionating woody biomass into more homogeneous substances, the ABS Process™ holds potential as an economically viable pathway for capturing sustainable, renewable value not currently realized from lignocellulosic biomass. © 2011 by the authors.

Non-food plant biomass is subjected hot-water extraction in a pressurized vessel at an elevated temperature up to about 250 C. without addition of reagents, to yield an aqueous extract containing hemicellulosic components and a lignocellulosic residue. The process leaves the lignocellulose substantially intact, but with the hemicellulosic content largely removed. The separated aqueous extract or liquor is concentrated and purified, and long-chain sugars are reduced into monomer saccharides. The lignocellulosic residue may be further processed, to yield a useful fibrous material that is highly resistant to sorption of water. This material may be used for composite materials that resist water degradation, or may be used to produce a higher thermal-yield, water-resistant fuel, or may be used as bioconversion feedstock for producing high-value, lignocellulosic derivatives.

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