Le Floch A.,Laboratoire dElectronique Quantique |
Le Floch A.,University of Rennes 1 |
Ropars G.,University of Rennes 1 |
Lucas J.,CNRS Chemistry Institute of Rennes |
And 4 more authors.
Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences | Year: 2013
The crystal recently discovered in the 1592 sunken Elizabethan ship is shown to be an Iceland spar. We report that two main phenomena, with opposite effects, explain the good conservation and the evolution of this relatively fragile calcite crystal. We demonstrate that the Ca2+-Mg2+ ion exchanges in such a crystal immersed in sea water play a crucial role by limiting the solubility, strengthening the mechanical properties of the calcite, while the sand abrasion alters the crystal by inducing roughness of its surface. Although both phenomena have reduced the transparency of the Alderney calcite crystal, we demonstrate that Alderney-like crystals could really have been used as an accurate optical sun compass as an aid to ancient navigation, when the Sun was hidden by clouds or below the horizon. To avoid the possibility of large magnetic errors, not understood before 1600, an optical compass could have helped in providing the sailors with an absolute reference. An Alderney-like crystal permits the observer to follow the azimuth of the Sun, far below the horizon, with an accuracy as great as ±1°. The evolution of the Alderney crystal lends hope for identifying other calcite crystals in Viking shipwrecks, burials or settlements. Copyright © The Royal Society 2013.