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Provided herein are methods of forming thin films. In some embodiments, to form a thin film, a precursor adsorption layer including an organic ligand is formed by supplying a precursor including a metal or silicon central atom, and the organic ligand onto a lower structure. An intermediate result layer is formed by supplying a non-oxidant onto the precursor adsorption layer. In forming the intermediate result layer, the organic ligand included in the precursor adsorption layer is substituted with a substituent. An oxide film including the central atom is formed from the intermediate result layer by supplying an oxidant onto the intermediate result layer.


Patent
The Chemo Sero Therapeutic Research Institute, Tokyo Medical, Dental University, Sapporo Medical University and Adeka Corporation | Date: 2016-03-16

A hybrid gel comprising a particulate decellularized tissue (obtained by pulverizing animal-derived biological tissues that are decellularized (decellularized biological tissues)), fibrinogen and thrombin; a cell culture material comprising the hybrid gel; a method for preparing the hybrid gel; and a kit comprising a particulate decellularized tissue and a biological tissue adhesive are provided. The hybrid gel of the present invention exerts the effect to promote differentiation and gain of function of stem cells and the therapeutic effect to a variety of diseases.


Provided are: a clarifying agent composition in a powder form which has excellent fluidity; and a polyolefin-based resin composition capable of yielding a molded article having excellent clarity. The clarifying agent composition is obtained by heating a mixture in a range of 80 to 180C, the mixture comprising: not less than 85% by mass of a benzylidene sorbitol compound represented by the following Formula (1):^(1), R^(2), R^(3) and R^(4) each independently represent a hydrogen atom, a halogen atom, a cyano group or an alkyl group having 1 to 4 carbon atoms);5 to 10% by mass of tetrakis[3(3,5-di-tert-butyl-4-hydroxyphenyl)propionyloxymethyl]methane; and 6 to 9% by mass of a lubricant.


Patent
Adeka Corporation | Date: 2016-01-13

Provided is a method of producing a resin composition for a coated member which shows excellent adhesion with a coating film after a plasma treatment and can have suppressed yellowing. The method of producing a resin composition for a coated member, which resin composition comprises a polymer obtained by polymerization of a monomer having an ethylenically unsaturated bond and a thermoplastic elastomer, is characterized by comprising the steps of:(A) adding, before or during said polymerization of said monomer having an ethylenically unsaturated bond, a phenolic antioxidant represented by the following Formula (1), that is masked with an organoaluminum compound, to at least one of a catalyst system, a polymerization system and a piping, and performing said polymerization such that said phenolic antioxidant is incorporated in an amount of 0.001 to 0.5 parts by mass with respect to a total of 100 parts by mass of said polymer obtained by said polymerization of said monomer having an ethylenically unsaturated bond and said thermoplastic elastomer; and(B) melt-kneading said polymer obtained by said polymerization of said monomer having an ethylenically unsaturated bond with said thermoplastic elastomer:_(1) and R_(2) each independently represent a hydrogen atom, an alkyl group having 1 to 5 carbon atoms which is optionally branched or an arylalkyl group having 7 to 9 carbon atoms; and R represents an alkyl group having 1 to 30 carbon atoms which is optionally branched, an alkenyl group having 2 to 30 carbon atoms which is optionally branched, a cycloalkyl group having 3 to 12 carbon atoms which is optionally substituted or an aryl group having 6 to 18 carbon atoms which is optionally substituted);(C) molding the composition from step B into an article.


Patent
Adeka Corporation | Date: 2016-03-25

Disclosed is a novel compound represented by formula (1) below. In the formula, A represents an optionally substituted aromatic hydrocarbon ring or aromatic heterocyclic group, B represents a group including a chain of one to four pieces of one or more groups selected from groups represented by specific formulae (B-1) to (B-13) (such as CC or NN, specifically see the description), R1 to R3 each represent an optionally substituted hydrocarbon or hydrocarbonoxy group, at least one of R1 to R3 represents an optionally substituted hydrocarbonoxy group, R4 and R5 each represent an optionally substituted hydrocarbon group, R4 and R5 may be linked together to form a ring, and R4 and R5 may be each independently linked with A to form a ring.


Patent
Adeka Corporation | Date: 2016-10-19

A substrate excellent in weatherability and adhesion to a coating applied thereon is provided. The substrate contains (a) 100 parts by mass of a polyolefin resin, (b) 0.01 to 0.5 parts by mass of an aromatic phosphoric ester metal salt having general formula (1), and (c) 0.02 to 0.5 parts by mass of a hindered amine compound, preferably a compound having general formula (2), and optionally preferably (d) 0.02 to 0.5 parts by mass of a benzoate light stabilizer having general formula (4). The structures of general formulae (1), (2), and (4) are as defined in the description.


Patent
Adeka Corporation | Date: 2016-08-10

Provided is an ultraviolet-absorbing polycarbonate which exhibits excellent heat resistance as well as excellent weather resistance without showing a reduction in its performance or contaminating a processing facility during processing. The ultraviolet-absorbing polycarbonate is represented by the following Formula (1):^(1) represents a linear or branched alkylidene group having 2 to 10 carbon atoms or the like; R^(1) to R^(4) each independently represent a hydrogen atom or the like; and A^(1) and A^(2) each independently represent a group represented by the following Formula (2), (3) or the like:^(1) represents a linear or branched alkylene group having 1 to 18 carbon atoms or the like; R^(5) to R^(8) each represent a linear or branched alkyl group having 1 to 12 carbon atoms or the like; R^(9) and R^(10) each represent a linear or branched alkyl group having 1 to 12 carbon atoms or the like; and R^(11) represents a hydrogen atom or the like)^(12) and R^(13) each represent a hydrogen atom or the like)].


Provided is a novel phosphorus-containing compound represented by general formula (I). The compound has reactivity with a glycidyl group and is therefore capable of providing a curing epoxy resin composition that is expected to achieve flame retardation and reduction of dielectric constant.^(1), R^(2), R^(3), and R^(4) are each hydrogen, alkyl, or aryl; R^(5) is alkyl, alkanediyl, alkanetriyl, alkanetetrayl, or an aromatic group; X is oxygen or sulfur; Y is oxygen , sulfur, or =NR; and R is hydrogen, alkyl, or aryl.


Patent
Adeka Corporation | Date: 2016-07-06

The invention provides a dye-sensitized solar cell which includes a working electrode and a counter electrode facing each other with an electrolyte layer therebetween, the working electrode having a dye-supporting metal oxide electrode composed of a metal oxide layer having a dye supported thereon. The dye contains a cyanine dye, and the electrolyte of the electrolyte layer contains a cobalt-based electrolyte. It is preferred to use at least one cyanine dye represented by general formula (1) below as the cyanine dye.^(q-) represents a q-valent anion, wherein q represents 1 or 2, and p represents a coefficient for maintaining overall charge neutrality.)


Patent
Adeka Corporation | Date: 2016-08-31

Provided is a method of producing a stabilized polymer by which, while imparting sufficient stabilizing effect to the polymer of a monomer having an ethylenically unsaturated bond, the amount of residual solvent in the polymer can be reduced and the occurrence of foaming can be inhibited. The method of producing a stabilized polymer comprises the step of adding an antioxidant having a melting point of 70C or lower to a catalyst system or a polymerization system before or during polymerization of a monomer having an ethylenically unsaturated bond such that 0.005 to 0.5 parts by mass of the antioxidant is incorporated with respect to 100 parts by mass of a polymer obtained by the polymerization of the monomer having an ethylenically unsaturated bond.

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