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Nara-shi, Japan

Yuasa J.,8916 5 Takayama Ikoma | Ogawa T.,8916 5 Takayama Ikoma | Kawai T.,8916 5 Takayama Ikoma
Chemical Communications | Year: 2010

Slow evaporation of a chloroform-n-hexane solution of 2-(anthracene-9- ylethynyl)-1-methylbenzimidazole (BzIm-An) yields cyclodimer (BzIm-An) 2 as crystals; the cyclodimerization is then dramatically accelerated on the product crystal faces. © 2010 The Royal Society of Chemistry.


Inukai N.,8916 5 Takayama Ikoma | Yuasa J.,8916 5 Takayama Ikoma | Kawai T.,8916 5 Takayama Ikoma
Chemical Communications | Year: 2010

Carbazole ligand (Im2Cz) forms a dimer complex ([(Im 2Cz)4-Zn2+]2) that has multiple π-stacking interactions, after which the complex changes to a simple (Im 2Cz)3-Zn2+ complex that has no π-stacking carbazole ring via increased Zn2+ concentration. © 2010 The Royal Society of Chemistry.

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